A General Route to Tri-tert-butoxytungsten Alkylidyne Complexes. Scission of Acetylenes by Ditungsten Hexa-tert-butoxide

Organometallics

Volumn 4, Issue 1, 1985, Pages 74-83

  Listemann, Mark L ^a   Schrock, Richard R ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002595095     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00120a014     Document Type: Article

References (28)

1. Multiple Metal Carbon Bonds. 35. For part 34 see: McCullough, L. G.; Schrock, R. R. J. Am. Chem. Soc. 1984, 106, 4067.
2. Wengrovius, J. H.; Sancho, J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 3932. (b) Sancho, J.; Schrock, R. R. J. Mol. Catal. 1982, 15, 75.
3. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S. M.; Pedersen, S. F. Organometallics 1982, 1, 1645.
4. Schrock, R. R. Acc. Chem. Res. 1979, 12, 98.
5. Schrock, R. R.; Listemann, M. L.; Sturgeoff, L. G. J. Am. Chem. Soc. 1982, 104, 4291.
6. Chisholm, M. H.; Hoffman, D. M.; Huffman, J. C. Inorg. Chem. 1983, 22, 2903.
7. Cotton, F. A.; Schwotzer, W.; Shamshoum, E. S. Organometallics 1983, 2, 1167. (b) J. Am. Chem. Soc. 1340.
8. Pedersen, S. F. Ph.D. Thesis, Massachusetts Institute of Technology, 1983.
9. Chisholm, M. H.; Huffman, J. C.; Marchant, N. S. J. Am. Chem. Soc. 1983, 105, 6162.
10. Holmes, S. J.; Clark, D. N.; Turner, H. W.; Schrock, R. R. J. Am. Chem. Soc. 1982, 104, 6332.
11. Clauss, A. D.; Shapley, J. R.; Wilker, C. N.; Hoffmann, R. Organometallics 1984, 3, 619. (b) King, R. B.; Harmon, C. A. Inorg. Chem. 1976, 15, 879. (c) Fritch, J. R.; Vollhardt, K. P. C.; Thompson, M. R.; Day, V. W. J. Am. Chem. Soc. 1979, 101, 2768. (d) Fritch, J. R.; Vollhardt, K. P. C. Angew. Chem., Int. Ed. Engl. 1980, 19, 559. (e) Yamazaki, H.; Wakatsuki, Y.; Aoki, K. Chem. Lett. 1979, 1041. (f) Gardner, S. A.; Andrews, P. S.; Rausch, M. D. Inorg. Chem. 1973, 12, 2396.
12. Park, J. T.; Shapley, J. R.; Churchill, M. R.; Bueno, C. J. Am. Chem. Soc. 1973, 105, 6182.
13. Hoffman, D. M.; Hoffmann, R.; Fisel, C. R. J. Am. Chem. Soc. 1982, 104, 3358.
14. Huq, F.; Mowat, W.; Skapski, A. C.; Wilkinson, G. J. Chem. Soc., Chem. Commun. 1971, 1477. (b) Mowat, W.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1973, 1120.
15. Chisholm, M. H.; Cotton, F. A.; Extine, M.; Stults, B. R. Inorg. Chem. 1976, 15, 2252. (b) Chisholm, M. H.; Cotton, F. A.; Extine, M. W.; Murillo, C. A. J. Am. Chem. Soc. 1978, 17, 696. (c) Andersen, R. A.; Galyer, A. L.; Wilkinson, G. Angew. Chem., Int. Ed. Engl. 1976, 15, 609.
16. Jaouen, G.; Marinetti, A.; Saillard, J.-Y.; Sayer, B. G.; McGlinchey, M. J. Organometallics 1982, 1, 225. (b) Iwashita, Y.; Tamura, F.; Wakamatsu, H. Bull. Chem. Soc. Jpn. 1970, 43, 1520. (c) Dickson, R. S.; Pain, G. N. J. Chem. Soc., Chem. Commun. 1979, 277.
17. Churchill, M. R.; Ziller, J. W.; Freudenberger, J. H.; Schrock, R. R. Organometallics 1984, 3, 1554. (b) Freudenberger, J. H.; Schrock, R. R.; Churchill, M. R.; Rheingold, A. L.; Ziller, J. W. Organometallics 1984, 3, 1563.
18. Churchill, M. R.; Ziller, J. W.; McCullough, L. G.; Pedersen, S. F.; Schrock, R. R. Organometallics 1983, 2, 1046.
19. Churchill, M. R.; Fettinger, J. C.; McCullough, L. G.; Schrock, R. R. J. Am. Chem. Soc. 1984, 106, 3356. (b) Churchill, M. R.; Ziller, J. W.; Pedersen, S. F.; Schrock, R. 485:00R. J. Chem. Soc., Chem. Commun. 1984, 485. (c) Schrock, R. R.; Pedersen, S. F.; Churchill, M. R.; Ziller, J. W. Organometallics 1984, 3, 1574. (d) We have shown recently that addition of a disubstituted acetylene to W(CCMe3)(O2CR)3(R = Me, etc.) yields an η3-cyclopropenyl complex: Freudenberger, J. H.; Schrock, R. R. Churchill, M. R.; Ziller, J. W., to be submitted for publication.
20. Chisholm, M. H.; Folting, K.; Hoffman, D. M.; Huffman, J. C. J. Am. Chem. Soc. 1984, 106, 6794.
21. Chisholm, M. H.; Hoffman, D. M.; Huffman, J. C. J. Am. Chem. Soc. 1984, 106, 6806.
22. Negishi, E.-I. “Organometallics in Organic Synthesis Wiley: New York, 1980; Vol. 1, 65.
23. Jones, K.; Lappert, M. F. J. Organomet. Chem. 1965, 3, 295.
24. Hutton, J.; Potts, B.; Southern, P. F. Synth. Commun. 1979, 9(9), 789.
25. Delavarenne, Y.; Viehe, H. G. Chem. Ber. 1970, 103, 1209.
26. Greene, T. W. “Protective Groups in Organic Synthesis Wiley: New York, 1981; p 40.
27. Brandsma, L. “Preparative Acetylenic Chemistry Elsevier: Amsterdam, 1971; p 148.
28. Brandsma, L.; Verkruijsse, H. D. “Studies in Organic Chemistry 8. Synthesis of Acetylenes, Allenes, and Cumulenes”; Elsevier: Amsterdam, 1981; p 109.