Evidence for actinide metal to ligand π backbonding. Density functional investigations of the electronic structure of [{(NH2)3(NH3)U}2(μ 2-η2:η2-N2)]

Chemical Communications

Volumn , Issue 16, 1998, Pages 1665-1666

  Kaltsoyannis, Nikolas ^a   Scott, Peter ^b  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

^b UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002546333     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a803833c     Document Type: Article

References (14)

1. J. B. Brennan, J. C. Green and C. M. Redfern, J. Am. Chem. Soc., 1989, 111, 2373.
2. D. L. Clark, S. K. Grumbine, B. L. Scott and J. G. Watkin, Organometallics, 1996, 15, 949.
3. R. J. Butcher, D. L. Clark, S. K. Grumbine, B. L. Scott and J. G. Watkin, Organometallics, 1996, 15, 1488.
4. N. Kaltsoyannis and B. E. Bursten, J. Organomet. Chem., 1997, 528, 19.
5. P. Roussel and P. Scott, J. Am. Chem. Soc., 1998, 120, 1070.
6. N. Kaltsoyannis, J. Chem. Soc., Dalton Trans., 1996, 1583.
7. G. te Velde and E. J. Baerends, J. Comput. Phys., 1992, 99, 84.
8. ADF〈2.3〉, Department of Theoretical Chemistry, Vrije Universiteit, Amsterdam, 1997.
9. T. Ziegler, V. Tschinke, E. J. Baerends, J. G. Snijders and W. Ravenek, J. Phys. Chem., 1989, 93, 3050.
10. S. H. Vosko, L. Wilk and M. Nusair, Can. J. Phys., 1980, 58, 1200.
11. A. Becke, Phys. Rev. A, 1988, 38, 3098.
12. J. P. Perdew, Phys. Rev. B, 1986, 33, 8822.
13. R. S. Mulliken, J. Chem. Phys., 1955, 23, 1833.
14. N. Kaltsoyannis, J. Chem. Soc., Dalton Trans., 1997, 1 (Perspective article).