Mass spectrometric fragmentation reactions of aliphatic carboxamides. A reinvestigation using metastable ions reveals new rearrangements

European Journal of Mass Spectrometry

Volumn 4, Issue 1, 1998, Pages 63-78

  Kreft, Dirk ^a   Grützmacher, Hans Friedrich ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Carboxamides; Fragmentation mechanism; Functional group migration; MIKES; Rearrangement

Indexed keywords

EID: 0002508181     PISSN: 14690667     EISSN: None     Source Type: Journal    
DOI: 10.1255/ejms.192     Document Type: Article

References (18)

1. (a) J. Gilpin, Anal. Chem. 31, 935 (1959);
2. (b) J. Munch-Petersen, Acta Chem. Scand. 12, 2007 (1958).
3. H. Budzikiewicz, C. Djerassi, D.H. Williams, Mass Spectrometry of Organic Compounds. Holden-Day Inc., San Francisco, CA (1967).
4. M. Abebe, A. Maccoll and R.D. Bowen, Eur. Mass Spectrom. 3, 197 (1997).
5. (a) M. Witt and H.-F. Grützmacher, Int. J. Mass Spectrom. Ion Proc. 164, 93 (1997);
6. (b) M. Witt and H.-F. Grützmacher, Int. J. Mass Spectrom. Ion Proc., in print.
7. (a) D.J. McAdoo, C.E. Hudson, T. Lin, L.L. Griffin and J.C. Traeger, Int. J. Mass Spectrom. Ion Proc. 87, 61 (1989);
8. (b) O. Lefevre, N. Mollova and P. Longevialle, Org. Mass Spectrom. 27, 589 (1992);
9. (c) D.J. Harvey, Org. Mass Spectrom. 28, 287 (1993);
10. (d) I. Vidavsky, R.A. Chorush, P. Longevialle and F.W. McLafferty, J. Am. Chem. Soc. 116, 5865 (1994).
11. (a) T. Weiske and H. Schwarz, Chem. Ber. 116, 323 (1983);
12. (b) E. Gosku, T. Weiske, H. Halim and H. Schwarz, J. Am. Chem. Soc. 106, 1167 (1984);
13. (c) T. Weiske, H. Halim and H. Schwarz, Chem. Ber. 118, 495 (1985).
14. Organikum, 16. Auflage, VEB Verlag d. Wissenschaften, Berlin (1988).
15. th Edn. University Science Books, Mill Valley, CA (1993).
16. (a) D.J. McAdoo and C.E. Hudson, J. Am. Chem. Soc. 103, 7710 (1981);
17. (b) C.E. Hudson, T. Lin and D.J. McAdoo, Org. Mass Spectrom. 22, 311 (1987).
18. N. Mollova and P. Longevialle, J. Am. Soc. Mass Spectrom. 1, 238 (1990).