Stereochemical proof of the existence of nucleophilic activation at a silicon atom in nucleophilic substitution reactions. Substitution of the SiCl-bond with retention of configuration

Journal of Organometallic Chemistry

Volumn 154, Issue 1, 1978, Pages 33-43

  Corriu, R J P ^a   Dabosi, G ^a   Martineau, M ^a  

^a Laboratoire de Chimie Bioorganique   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002444252     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)82789-8     Document Type: Article

References (21)

1. N.M.R. Study of Base-Catalyzed Hydrolysis of Trimethylfluorosilane
2. Kinetic and stereochemical evidence for nucleophilic assistance in the nucleophilic hydrolysis of chlorosilanes
3. 725. Nucleophilic substitution reactions of organosilicon compounds. Part II. Reaction mechanisms of some sterically hindered organosilicon chlorides
4. Hydrolysis and intermolecular silyl exchange in N-(trimethylsilyl)imidazole and N-(trimethylsilyl)-2-methylimidazole
5. Displacement Reactions of Phosphorus(V) Compounds and Their Pentacoordinate Intermediates
6. Mécanisme de la racémisation des chlorosilanes. Étude cinétique: Détermination de l'ordre et de l'entropie d'activation