X-ray diffraction and spectroscopic studies of the light-induced metastable state of a ethylenediamine nitrosyl ruthenium complex

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 14, 2000, Pages 2425-2431

  Kawano, Masaki ^a,d   Ishikawa, Ayako ^a,b   Morioka, Yoshiyuki ^a,c,d   Tomizawa, Hiroshi ^a,b   Miki, Ei Ichi ^a,b   Ohashi, Yuji ^a,b  

^a JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c SAITAMA UNIVERSITY   (Japan)

^d RIKKYO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002382948     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b001132k     Document Type: Article

References (49)

1. U. Hauser, V. Oestreich and H. D. Rohnveck, Z. Pliys. A, 1977,280, 17.
2. T. Woike, W. Krasser, P. S. Bechthold and S. Haussühl, Phys. Rev. Lett., 1984,53, 1767.
3. H. Zöllner, W. Krasser, P. S. Bechthold and S. Haussühl, Chem. Phys. Lett., 1989,161; 497.
4. S. Haussühl, G. Schetter and T. Woike, Opt. Commun., 1995, 114, 219.
5. J. A. Guida, P. J. Aymonino, O. E. Piro and E. E. Castellano, Spectrochim. Acta, Part A, 1993,49, 535.
6. J. A. Güida, O. E. Piro and P. J. Aymonino, Inorg. Chem., 1995, 34, 4113.
7. Y. Morioka, Solid Stale Commun., 1992,82,505.
8. Y. Morioka, Spectrochim. Acta, Part A, 1994,50, 1499.
9. K. Ookubo, Y. Morioka, H. Tomizawa and E. Miki, J. Mol. Struct., 1996,379,241.
10. M. Rüdlinger, J. Schefer, G. Chevrier, N. Purer, H. U. Güdel, S. Haussühl,. G. Heger, P. Schweiss, T. Vogt, T. Woike and H. Zöllner, Z. Phys. B, 1991,83, 125.
11. M. Rüdlinger, J. Schefer, T. Vogt, T. Woike, S. Haussühl and H. Zöllner, Physlca B, 1992,180 and 181, 293.
12. M. R. Pressprich, M. A. White and P. Coppens, J. Am. Chem. Soc., 1993,115,6444.
13. M. R. Pressprich, M. A. White, Y. Vekhter and P. Coppens, J. Am. Chem. Soc., 1994,116,5233.
14. D. V. Fomitchev and P. Coppens, Inorg. Chem., 1996,35, 7021.
15. M. D. Carducci, M. R. Pressprich and P. Coppens, J. Am. Chem. Soc., 1997,119,2669.
16. P. Coppens, D. V. Fomitchev, M. D. Carducci and K. Gulp, J. Chem. Soc., Dation Trans., 1998, 6, 865.
17. D. V. Fomitchev, T. R. Furlani and P. Coppens, Inorg. Chem., 1998, 37,1519.
18. Y. Morioka, A. Ishikawa, H. Tomizawa and E. Miki, J. Chem. Soc., Dalton Trans., 2000, 5, 781.
19. H. Tomizawa, E. Miki, K. Mizumachi and T. Ishimori, (a) Bull. Chem. Soc. Jpn., 1994, 67, 1809;
20. (b) Bull. Chem. Soc. Jpn., 1994, 67, 1816.
21. SMART, Version 4.0, Siemens Industrial Automation, Inc., Madison, WI, 1995.
22. A CCD area detector has been found well suited for electron density studies on a reference crystal of an angiotensin II receptor antagonist, and the )J2 contamination, which affects area detectors but not well tuned conventional detectors, proves to be a negligible source of errors (P. Macchi, D. M. Proserpio, A. Sironi, R. Soave and R. Destro, J. Appl. Crystallogr., 1998, 31, 583). )J2 contamination is much more of a problem for small hard inorganic crystals than macromolecules. With the rotating anode setting used in our study it would be expected it to be evident in these data sets, though its effects will still be minor (K. Kirschbaum, A. Martin and A.A. Pinkerton, J. Appl. Crystallogr., 1997,30, 514)
23. -1 and high redundancy of data which is especially important for the SADABS program to work efficiently.
24. SAINT, Version 5.0, Siemens Industrial Automation, Inc., Madison, WI, 1998.
25. SHELXL 97, Crystal Structure Analysis Program, UNIX version, G. M. Sheldrick, 1993-1997, Release 97-2.
26. International Tables for Crystallography, ed. A. J. C. Wilson, Kluwer Academic Publishers, Dordrecht, 1992, vol. C, Tables 6.1.l.r (pp. 500-502), 4.2.6.8 (pp. 219-222), and 4.2.4.2 (pp. 193-199).
27. A. C. Larson, Crystallographic Computing, eds. F. R. Ahmed, S. R. Hall and C. P. Huber, Munksgaard, Copenhagen, 1970, pp. 291-294.
28. R. H. Blessing, Acta Crystallogr., Sect. A, 1995,51, 33.
29. The positional change of the Ru atom before/after modeling the metastable state is as follows. Before modeling (right after the initial Fourier difference calculation): Rul 0.107931 0.280042 0.303673. After the refinement including the metastable model: Rul 0.107954 0.280017 0.303671. This indicates that the Ru atom position shifted by less than 0.001 Å after the refinement. Likewise the N1 position of a nitrosyl group in the rigid group shifted by less than 0.001 Å.
30. -1.
31. -1, based on the results of polarized Raman spectroscopic studies using a 15N isotope (Y. Morioka, S. Takeda, H. Tomizawa and M. Ei-ichi, Cheat. Phys. Lett., 1998, 292, 625);
32. GS vibrations, L. Tosi, Spectrochim. Ada., Part A, 1973, 29, 353;
33. J. B. Bates and R. K. Khanna, Inorg. Client, 1970, 9, 1376;
34. MS vibrations based on Raman scattering measurement, W. Krasser, Th. Woike, S. Haussühl, J. Kühl and A. Breitschwerdt, J. Roman Spectrosc., 1986, 17, 83;
35. MS vibrations based on polarized IR absorption measurement, J. A. Guida, P. J. Aymonino, O. E. Piro and E. E. Castellano, Spectrochim. Ada, Pan A, 1993,59,535.
36. U. Hauser, V. Oestreich and H. D. Rohnveck, Z. Phys. A, 1977,280, 125;
37. Th. Woike, W. Kirchner, H. Kim, S. Haussühl, V. Rusanov, V. Angelov, S. Ormandjiev, Ts. Bonchev and A. N. F. Schroeder, Hyperfine Interact., 1993,7, 265.
38. C. Terrile, O. R. Nascimento, I. J. Moraes, E. E. Castellano, O. E. Piro, J. A. Guida and P. J. Aymonino, Solid State Commun. 1990,73, 481.
39. 2O, réf. 19(6) 1.727(6) (X = Cl), 1.738(5) (X = Br), 1.736(15) Å (X = I) in [RuXj(en)(NO)], H. Tomizawa, K. Harada, E. Miki, K. Mizumachi, T. Ishimori
40. A. Urushiyama and M. Nakahara, Bull. Client. Soc. Jpn., 1993, 66 1658.
41. D. R. Hershbach and V. W. Laurie, J. Solid State Phys., 1961, 35 458.
42. Another possible reason for the lowering of frequency for v(NO) can be a rehybridization of the lone pair at O on co-ordination. To elucidate the electronic state of the MS, theoretical calculation will be necessary.
43. M. J. Cleare, H. P. Fritz and W. P. Griffith, Spectrochim. Ada, Part /f,l 972,28,2013.
44. Y. Ohashi, K. Yanagi, T. Kurihara, Y. Sasada and Y. Oheo, J. Am. Chem. Soc.,~1981, 103, 5805;
45. Y. Ohashi, A. Uchida, Y. Sasada and Y. Ohgo, Ada Crystallogr., Sect. B, 1983, 39, 54;
46. Y. Ohashi, Ace. Chem. Res., 1988, 21, 268;
47. K. Sawada, D. Hashizume, A. Sekine, H. Uekusa, K. Kato, Y. Ohashi, K. Kakinuma and Y. Ohgo, Acta Crystallogr., Sect. B, 1996, 52, 303.
48. J. Dunitz, X-Ray Analysis and the Structure of Organic Molecules, VCH, New York, 1995, p. 248.
49. B. Delley, J. Schefer and Th. AVoike, J. Chem. Phys., 1997, 107(32), 10067.