Intramolecular Luminescence Quenching in Amino Acid Bridged Ruthenium(II)-Copper(II) Complexes with Negligible Ground-State Coupling

European Journal of Inorganic Chemistry

Volumn , Issue 7, 1998, Pages 957-963

  Geißer, Bernd ^a   Alsfasser, Ralf ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Amino acids; Bioinorganic chemistry; Copper; Luminescence; Ruthenium

Indexed keywords

AMINO ACIDS; ASCORBIC ACID; COPPER COMPOUNDS; EQUILIBRIUM CONSTANTS; GROUND STATE; QUENCHING; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

AMINO-ACIDS; BIOINORGANIC CHEMISTRY; BIPYRIDYL; DIAMINO ACIDS; DIAMINOPROPIONIC ACID; HETERO BIMETALLIC COMPLEXES; LUMINESCENCE QUENCHING; METAL CENTRES; STATE COUPLINGS; [CARBONYL;

LUMINESCENCE;

EID: 0002354395     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199807)1998:7<957::AID-EJIC957>3.0.CO;2-6     Document Type: Article

References (49)

1. A. J. Bard, M. A. Fox, Acc. Chem. Res. 1995, 28, 141-145.
2. T. J. Meyer, Acc. Chem. Res. 1989, 22, 163-170.
3. V. Balzani, A. Juris, M. Venturi, S. Campagna, S. Serroni, Chem Rev. 1996, 96, 759-833.
4. M. A. Fox, M. Chanon, Photoinduced Electron Transfer Reactions, Elsevier, Amsterdam, 1988, part D.
5. E. Kimura, X. Bu, M. Shionoya, S. Wada, S. Maruyama, Inorg. Chem. 1992, 31, 4542-4546.
6. E. Kimura, S. Wada, M. Shionoya, Y. Okazaki. Inorg. Chem. 1994, 33, 770-778.
7. R. Alsfasser, R. van Eldik, Inorg. Chem. 1996, 35, 628-636.
8. D. S. Sigman, D. R. Graham, V. D'Aurora, A. M. Stern, J. Biol. Chem. 1979, 254, 12269-12272.
9. D. S. Sigman, Acc. Chem. Res. 1986, 19, 180-186.
10. T. B. Therderahn, M. D. Kuwabara, T. A. Larsen, D. S. Sigman, J. Am. Chem. Soc. 1989, 111, 4941-4946
11. T. C. Strekas, A. D. Baker, O. Harripersad-Morgan, J. Coord. Chem 1997, 34, 77-85.
12. A. M. Pyle, J. P. Rehmann, R. Meshoyrer, C. V. Kumar, N. J. Turro, J. K. Barton, J. Am. Chem. Soc. 1989, 111, 3051-3058.
13. A. Kirsch-De Mesmaeker, J.-P. Lecomte, J. M. Kelly, Top. Curr. Chem. 1995, 177, 25-76.
14. R. Tamilarasan, D. R. McMillin, Inorg. Chem. 1990, 29, 2798-2802.
15. M. Milkevitch, H. Storrie, E. Brauns, K. J. Brewer, B. W. Shirley, Inorg. Chem. 1997, 36, 4534-4538.
16. B. M. Peek, G. T. Ross, S. W. Edwards, G. J. Meyer, T. J. Meyer, B. W Erickson, Int. J. Pept. Protein Res. 1991, 38, 114-123.
17. B. Geißer, A. Ponce, J. R. Winkler, R. Alsfasser, manuscript in preparation.
18. S. L. Mecklenburg, D. G. McCafferty, J. R. Schoonover, B. M. Peek, B. W. Erickson, T. J. Meyer, Inorg. Chem. 1994, 33, 2974-2983.
19. R. S. Drago, Physical Methods for Chemists, 2nd ed., Saunders College Publishing, Ft. Worth, 1977, chapter 12.
20. R. J. Abraham, J. Fisher, P. Loftus, Introduction to NMR Spectroscopy, 2nd ed., John Wiley and Sons, Chichester, New York, Brisbane, Toronto, Singapore, 1993.
21. B. J. Hathaway, A. A. G. Tomlinson, Coord Chem. Rev. 1970, 5, 1.
22. B. J. Hathaway in Comprehensive Coordination Chemistry (Eds.: S. G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon Press, Oxford, 1987, vol. 5, chapter 53.
23. S. V. Deshpandc, T. S. Srivastava, Inorg. Chim. Acta 1983, 78, 75-80.
24. K. Kalyanasundaram, Coord. Chem. Rev. 1982, 46, 159-244.
25. A. Juris, V. Balzani, F. Barigelletti, S. Campagna, P. Belser, A. von Zelewsky, Coord. Chem. Rev. 1988, 84, 85-277.
26. M. J. Root, B. P. Sullivan, T. J. Meyer, E. Deutsch, Inorg. Chem 1985, 24, 2731-2739.
27. N. Sutin, Prog. Inorg. Chem. 1983, 30, 441.
28. N. S Hush, Electrochim. Acta 1968, 13, 1005.
29. C. Creutz, Prog. Inorg. Chem. 1983, 30, 1.
30. It should be noted out that one of the referees suggested that the intervalence bands for our compounds may appear at higher energies in the visible range of the spectrum where they could be obscured by other absorptions. This is possible since the reorganization energies should be large, as will be discussed in the following section. The compounds would then belong to the Robin-Day class II.
31. M. R. Robin, P. Day, Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
32. R. Sahai, D. A. Baucom, D. P. Rillema, Inorg. Chem. 1986, 25, 3843-3845.
33. F. Scandola, C. A. Bignozzi, M. T. Indelli in Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds (Eds.: K. Kalyanasundaram, M. Grätzel). Kluwer Academic Publishers, Dordrecht, Boston, London, 1993, vol. 14, p. 161-216.
34. Y. Yao, M. W. Perkovic, D. P. Rillema, C. Woods, Inorg. Chem. 1992, 31, 3956-3962.
35. M. A. Masood, D. J. Hodgson, Inorg. Chem 1993, 32, 4839-4844.
36. C.-W. Lee, F. C. Anson, Inorg. Chem 1984, 23, 837-844.
37. M. A. Augustin, J. K. Yandell, Inorg. Chem. 1979, 18, 577-583.
38. K. M. Davies, Inorg. Chem. 1983, 22, 615-619.
39. C.-W. Lee, F. C. Anson, J. Phys. Chem. 1983, 87, 3360-3362.
40. K. Kalyanasundaram in Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds (Eds.: K. Kalyanasundaram, M. Grätzel), Kluwer Academic Publishers, Dordrecht, Boston, London, 1993, vol. 14, p. 113-160.
41. W. F. Wacholtz, R. A. Auerbach, R. H. Schmehl, Inorg. Chem. 1987, 26, 2989-2994.
42. H. G. O. Becker, Einführung in die Photochemie, 3. Auflage, Deutscher Verlag der Wissenschaften, Berlin, 1991, chapter 4.3.
43. V. Balzani, M. Meastri in Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds (Eds.: K. Kalyanasundaram, M. Grätzel), Kluwer Academic Publishers, Dordrecht, Boston, London, 1993, vol. 14, p. 15-70.
44. R. H. Schmehl, R. A. Auerbach, W. F. Wacholtz, C. M. Elliott, R. A. Freitag, J. W. Merkert, Inorg. Chem. 1986, 25, 2440-2445.
45. J. Polster, H. Lachmann, Spectrometric Titrations, VCH, Weinheim, 1989, p. 344.
46. A. M. Josceanu, P. Moore, S. C. Rawle, P. Sheldon, S. M. Smith, Inorg. Chim. Acta 1995, 240, 159-168.
47. L. Zékâny, I. Nagypál, G. Peintler, PSEQUAD, University Szeged, 1990.
48. S. H. Laurie in Comprehensive Coordination Chemistry (Eds.: S. G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon Press, Oxford, 1987, vol. 2, chapter 20.2.
49. A. H. Osman. A. Vogler in Photochemistry and Photophysics of Coordination Compounds (Eds.: H. Yersin, A. Vogler), Springer Verlag, Berlin, Heidelberg, 1997, p. 197-203.