Determination of selectivity for parallel reactions in supercritical fluids

Journal of Supercritical Fluids

Volumn 15, Issue 1, 1999, Pages 63-71

  Guo, Yang ^a   Akgerman, Aydin ^a  

^a Texas AandM University   (United States)

Author keywords

Hydroformylation; Partial molar enthalpy; Partial molar volume; Selectivity; Supercritical carbon dioxide

Indexed keywords

EID: 0002335214     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(98)00128-4     Document Type: Article

References (21)

1. D.A. Morgenstern, R.M. LeLacheur, D.M. Morita, S.L. Borkowsky, S. Feng, G.H. Brown, L. Luan, M.F. Gross, M.J. Burk, W. Tumas, Supercritical carbon dioxide as substitute solvent for chemical synthesis and catalysis, in: P.T. Anastas, T.C. Williamson (Eds.), Green Chemistry: Designing Chemistry for the Environment, ACS Symposium Series 626, 1996, p. 132.
2. G. Kaupp, Reactions in supercritical carbon dioxide, Angew. Chem., Int. Ed. Engl. 33 (1994) 1452.
3. P.E. Savage, S. Gopalan, T.I. Mizan, C.J. Martino, E.E. Brock, Reactions at supercritical conditions: Applications and fundamentals, AIChE J. 41 (1995) 1723.
4. M.E. Paulaitis, G.C. Alexandre, Reactions in supercritical fluids: A case study of the thermodynamic solvent effects on a Diels-Alder reaction in supercritical carbon dioxide, Pure Appl. Chem. 59 (1987) 61.
5. N.S. Isaacs, N. Keating, The rates of a Diels-Alder reaction in liquid and supercritical carbon dioxide, J. Chem. Soc., Chem. Commun. (1992) 876.
6. Y. Ikushima, N. Saito, M. Arai, Supercritical carbon dioxide as reaction medium: examination of its solvent effects in the near critical region, J. Phys. Chem. 96 (1992) 2293.
7. J.M. Tanko, J.F. Blackert, Free radical side chain bromination of alkyl aromatics in supercritical carbon dioxide, Science 263 (1994) 203.
8. J.M. DeSimone, Z. Guan, C.S. Elsbernd, Synthesis of fluoropolymers in supercritical carbon dioxide, Science 257 (1992) 945.
9. T. Pernecker, J.P. Kennedy, Carbocationic polymerizations in supercritical carbon dioxide. I. Exploratory experiments with isobutylene, Polymer Bull. 32 (1994) 537.
10. J.W. Rathke, R.J. Klingler, T.R. Krause, Propylene hydroformylation in supercritical carbon dioxide, Organometallics 10 (1991) 1350.
11. Y. Guo, A. Akgerman, Hydroformylation of propylene in supercritical carbon dioxide, Ind. Eng. Chem. Res. 36 (1997) 4581.
12. P.G. Jessop, T. Ikariya, R. Noyori, Homogeneous catalytic hydrogenation of supercritical carbon dioxide, Nature 368 (1994) 231.
13. T.W. Randolph, D.S. Clark, H.W. Blanch, J.M. Prausnitz, Enzymatic oxidation of cholestrol aggregates in supercritical carbon dioxide, Science 238 (1988) 61.
14. A. Marty, D. Combes, J.S. Condoret, Continuous reaction-separation process for enzymatic esterification in supercritical carbon dioxide, Biotech. Bioeng. 43 (1994) 497.
15. A.K. Dillow, S.L.J. Yun, D. Suleiman, D.L. Boatright, C.L. Liotta, C.A. Eckert, Kinetics of a phase transition catalysis reaction in supercritical fluid carbon dioxide, Ind. Eng. Chem. Res. 35 (1996) 1801.
16. L. Wender, P. Pino, Organic Syntheses via Metal Carbonyls, vol. 2, Wiley, New York, 1977, p. 44.
17. Y. Guo, A. Akgerman, Infinite dilution partial molar volumes of butanal and 2-methylpropanal in supercritical carbon dioxide, Chem. Eng. Data, in press.
18. B. Cornils, Hydroformylation, oxo-synthesis, roelen reaction, in: J. Falbe (Ed.), New Synthesis with Carbon Monoxide, Springer, Berlin, 1980, p. 16.
19. Y. Guo, Hydroformylation in supercritical carbon dioxide, Ph.D. Dissertation, Texas A&M University, 1998.
20. S.M. Walas, Phase Equilibrium in Chemical Engineering, Butterworth, Boston, 1985.
21. M.G. Evens, M. Polanyi, Some applications of the transition state methods to the calculation of reaction velocities, Trans. Faraday Soc. 31 (1935) 875.