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For CO on transition metal surfaces, the valence d orbitals are actively involved in bonding and the heat of adsorption of the molecule varies between 90 and 20 kcal/ mol. On the other hand, for CO on noble metals, the participation of the valence d orbitals in bonding is weak, and the heat of adsorption of CO is relatively small (< 20 kcal/ mol): G.A. Somorjai, Introduction to Surface Chemistry and Catalysis (Wiley, New York, 1994) p. 310.
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The CO(2π*) orbitals are located at ∼ 1.8 eV above the vacuum level:
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