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Volumn 12, Issue 41, 1971, Pages 3777-3780

The stereochemistry of additions of grignard reagents to alkynols

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EID: 0002291862     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)97286-7     Document Type: Article
Times cited : (31)

References (13)
  • 1
    • 84918225142 scopus 로고    scopus 로고
    • Although it is convenient to speak of addition to alcohols, it should be remembered that in the Grignard solutions, the hydroxyl function is present as a magnesium salt.
  • 4
    • 0004250303 scopus 로고
    • 1 substituents, however) are configurationally stable under conditions similar to those used in this work, J. Zabicky, Wiley-Interscience, London, Chapter 2
    • (1970) The Chemistry of Alkenes , vol.2
    • Richey1
  • 6
    • 84918225141 scopus 로고    scopus 로고
    • Small amounts of 5-hexyn-1-ol also were isolated from reactions of 7 in THF.
  • 7
    • 84918225140 scopus 로고    scopus 로고
    • The experimental error was considerable because less than 1.0 D was incorporated and the analysis was of a mixture of 13 and 14. It is not certain if any significant amount of deuterium was present in the vinyl position.
  • 12
    • 84918225139 scopus 로고    scopus 로고
    • 2, etc.).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.