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Volumn 617-618, Issue , 2001, Pages 182-208

The preparation of imidazolidinone and oxazolidinone chelated carbene complexes

Author keywords

Carbene complexes; Chelated Fischer carbene complexes; Chromium; Imidazaolidinone; Oxazolidinone; Tungsten

Indexed keywords


EID: 0002235475     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00734-8     Document Type: Article
Times cited : (20)

References (49)
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    • For recent reviews on the synthetic applications of carbene complexes, see: (a) in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press
    • For recent reviews on the synthetic applications of carbene complexes, see: (a) W.D. Wulff, Comprehensive Organometallic Chemistry II, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press, vol. 12, 1995, pp. 469-547.
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  • 3
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    • (b) in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press
    • (b) M.P. Doyle, Comprehensive Organometallic Chemistry II, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press, vol. 12, 1995, pp. 387-420.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 387-420
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    • (c) in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press
    • (c) L.S. Hegedus, Comprehensive Organometallic Chemistry II, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon Press, vol. 12, 1995, pp. 549-599.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 549-599
    • Hegedus, L.S.1
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    • 0000536155 scopus 로고    scopus 로고
    • For a review, see
    • For a review, see: W.D. Wulff, Organometallics 17 (1998) 3116.
    • (1998) Organometallics , vol.17 , pp. 3116
    • Wulff, W.D.1
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    • -1) and thus both degrees of freedom present in alkoxy complex is absent in amino complexes. However, this barrier to rotation may not be present in reactive intermediates formed in the reactions of alkyl amino carbene complexes [5c].
    • -1) and thus both degrees of freedom present in alkoxy complex is absent in amino complexes. However, this barrier to rotation may not be present in reactive intermediates formed in the reactions of alkyl amino carbene complexes [5c].
  • 18
    • 0001529238 scopus 로고
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a)
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a) T.S. Powers, Y. Shi, K.J. Wilson, W.D. Wulff, J. Org. Chem. 59 (1994) 6882. (b) Y. Shi, W.D. Wulff, J. Org. Chem. 59 (1994) 5122. (c) Y. Shi, W.D. Wulff, G.P.A. Yap, A.L. Rheingold, J. Chem. Soc. Chem. Commun. (1996) 2601.(d) T.S. Powers, W. Jiang, J. Su, W.D. Wulff, B.E. Waltermire, A.L. Rheingold, J. Am. Chem. Soc. 119 (1997) 6438.(e) M.P. Parisi, A. Solo, W.D. Wulff, I. Guzei, A.L. Rheingold, Organometallics (1998) 17, 3696.
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    • Powers, T.S.1    Shi, Y.2    Wilson, K.J.3    Wulff, W.D.4
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    • (b)
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a) T.S. Powers, Y. Shi, K.J. Wilson, W.D. Wulff, J. Org. Chem. 59 (1994) 6882. (b) Y. Shi, W.D. Wulff, J. Org. Chem. 59 (1994) 5122. (c) Y. Shi, W.D. Wulff, G.P.A. Yap, A.L. Rheingold, J. Chem. Soc. Chem. Commun. (1996) 2601.(d) T.S. Powers, W. Jiang, J. Su, W.D. Wulff, B.E. Waltermire, A.L. Rheingold, J. Am. Chem. Soc. 119 (1997) 6438.(e) M.P. Parisi, A. Solo, W.D. Wulff, I. Guzei, A.L. Rheingold, Organometallics (1998) 17, 3696.
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    • Shi, Y.1    Wulff, W.D.2
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    • (c)
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a) T.S. Powers, Y. Shi, K.J. Wilson, W.D. Wulff, J. Org. Chem. 59 (1994) 6882. (b) Y. Shi, W.D. Wulff, J. Org. Chem. 59 (1994) 5122. (c) Y. Shi, W.D. Wulff, G.P.A. Yap, A.L. Rheingold, J. Chem. Soc. Chem. Commun. (1996) 2601.(d) T.S. Powers, W. Jiang, J. Su, W.D. Wulff, B.E. Waltermire, A.L. Rheingold, J. Am. Chem. Soc. 119 (1997) 6438.(e) M.P. Parisi, A. Solo, W.D. Wulff, I. Guzei, A.L. Rheingold, Organometallics (1998) 17, 3696.
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    • (d)
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a) T.S. Powers, Y. Shi, K.J. Wilson, W.D. Wulff, J. Org. Chem. 59 (1994) 6882. (b) Y. Shi, W.D. Wulff, J. Org. Chem. 59 (1994) 5122. (c) Y. Shi, W.D. Wulff, G.P.A. Yap, A.L. Rheingold, J. Chem. Soc. Chem. Commun. (1996) 2601.(d) T.S. Powers, W. Jiang, J. Su, W.D. Wulff, B.E. Waltermire, A.L. Rheingold, J. Am. Chem. Soc. 119 (1997) 6438.(e) M.P. Parisi, A. Solo, W.D. Wulff, I. Guzei, A.L. Rheingold, Organometallics (1998) 17, 3696.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 6438
    • Powers, T.S.1    Jiang, W.2    Su, J.3    Wulff, W.D.4    Waltermire, B.E.5    Rheingold, A.L.6
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    • (e)
    • For previous work on the synthetic utility of these complexes, see Ref. [3] and: (a) T.S. Powers, Y. Shi, K.J. Wilson, W.D. Wulff, J. Org. Chem. 59 (1994) 6882. (b) Y. Shi, W.D. Wulff, J. Org. Chem. 59 (1994) 5122. (c) Y. Shi, W.D. Wulff, G.P.A. Yap, A.L. Rheingold, J. Chem. Soc. Chem. Commun. (1996) 2601.(d) T.S. Powers, W. Jiang, J. Su, W.D. Wulff, B.E. Waltermire, A.L. Rheingold, J. Am. Chem. Soc. 119 (1997) 6438.(e) M.P. Parisi, A. Solo, W.D. Wulff, I. Guzei, A.L. Rheingold, Organometallics (1998) 17, 3696.
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    • It should be noted that the terms Z and E used here to describe the stereochemistry of the two rotamers about the carbene carbon-nitrogen bond are reversed from the usage employed by Fischer for this same purpose. (a)
    • It should be noted that the terms Z and E used here to describe the stereochemistry of the two rotamers about the carbene carbon-nitrogen bond are reversed from the usage employed by Fischer for this same purpose. (a) E. Moser, E.O. Fischer, J. Organomet. Chem. 16 (1969) 275. (b) E.O. Fischer, M. Leupold, Chem. Ber. 105 (1972) 599.
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    • (b)
    • It should be noted that the terms Z and E used here to describe the stereochemistry of the two rotamers about the carbene carbon-nitrogen bond are reversed from the usage employed by Fischer for this same purpose. (a) E. Moser, E.O. Fischer, J. Organomet. Chem. 16 (1969) 275. (b) E.O. Fischer, M. Leupold, Chem. Ber. 105 (1972) 599.
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    • Complex 16 was prepared according to the procedure for 15 Ref. [21].
    • Complex 16 was prepared according to the procedure for 15 Ref. [21].
  • 47
    • 33744583553 scopus 로고    scopus 로고
    • This material was obtained in 90% purity from Aidrich Chemical Company and used without purification.
    • This material was obtained in 90% purity from Aidrich Chemical Company and used without purification.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.