The first fluoroalkylation of amino acids and peptides in water utilizing the novel iodonium salt (CF3so2)2NI(Ph)CH2CF3

Chemical Communications

Volumn , Issue 20, 1998, Pages 2241-2242

  DesMarteau, Darryl D ^a   Montanari, Vittorio ^a  

^a CLEMSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002228253     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a805879b     Document Type: Article

References (21)

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17. From the reaction of 3 with aniline (2 equiv.) in boiling water, diphenylamine was isolated in 30% yield. Only trace amounts are obtained under the same conditions with diphenyliodonium bromide: F. M. Beringer, A. Brierley, M. Drexler, E. M. Gindler and C. C. Lumpkin, J. Am. Chem. Soc., 1953, 75, 2708.
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19. 3) -70.83, -70.86].
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21. 4Ph was 70%, representing more than 80% per alkylation step: D. D. DesMarteau, J. Sayers and V. Montanari, manuscript in preparation.