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Volumn 19, Issue 8, 1978, Pages 747-750

Mechanistic implications of the stereochemistry of singlet oxygen-olefin reactions

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EID: 0002165388     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)85384-3     Document Type: Article
Times cited : (47)

References (14)
  • 9
    • 84918281266 scopus 로고    scopus 로고
    • Our estimated heats of formation for compounds (1)-(4) and (6)-(9) are −15.6, −15.6, −37.9, −28.5, 10.8, 10.8, 16.5, and 16.5 kcal/mole, respectively.
  • 10
    • 84918281265 scopus 로고    scopus 로고
    • 1 when the methoxy is replaced with a methyl group. [In the biradical mechanism this latter result is explained in terms of the favorable thermodynamics.]
  • 13
    • 84918281264 scopus 로고    scopus 로고
    • M.J.S. Dewar, using nonbonded repulsion arguments, has also suggested that the trans perepoxide conformation is the more stable one (private communication).
  • 14
    • 84918281263 scopus 로고    scopus 로고
    • 2 on the carbon β to the methoxy substituent, a prediction clearly at variance with Conia's results.] As discussed in the text, we disagree with these conclusions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.