A vinylog of bis-fused TTF: Novel π-electron framework for metallic and superconducting organic solids

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 284, Issue , 1996, Pages 27-38

  Misaki, Yohji ^a   Higuchi, Natsuko ^a   Ohta, Takehiro ^a   Fujiwara, Hideki ^a   Yamabe, Tokio ^a   Mori, Takehiko ^b   Mori, Hatsumi ^c   Tanaka, Shoji ^c  

^a KYOTO UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c SUPERCONDUCTIVITY RESEARCH LABORATORY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BAND STRUCTURE; CALCULATIONS; CRYSTAL STRUCTURE; FERMI SURFACE; ORGANIC CONDUCTORS; ORGANOMETALLICS; PHASE TRANSITIONS; SUPERCONDUCTING MATERIALS; SUPERCONDUCTING TRANSITION TEMPERATURE; X RAY CRYSTALLOGRAPHY;

BAND CALCULATIONS; BIS-FUSED TETRATHIAFULVALENE; LIQUID HELIUM TEMPERATURE; VINYLOG;

ELECTRONIC STRUCTURE;

EID: 0002123039     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259608037908     Document Type: Article

References (35)

1. T. Ishiguro and K. Yamaji, Organic Superconductors (Springer-Verlag Berlin, Heidelberg, 1990); J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, and M.-H. Whangbo, Organic Superconductors, (Prentice Hall, New Jersey, 1992).
2. T. Ishiguro and K. Yamaji, Organic Superconductors (Springer-Verlag Berlin, Heidelberg, 1990); J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, and M.-H. Whangbo, Organic Superconductors, (Prentice Hall, New Jersey, 1992).
3. Reviews: K. Bechgaard, D. Jérome, Sci. Am., 24.7, 50 (1982); G. Saito, Phophorus, Sufur, and Silicon, 67, 345 (1992).
4. Reviews: K. Bechgaard, D. Jérome, Sci. Am., 24.7, 50 (1982); G. Saito, Phophorus, Sufur, and Silicon, 67, 345 (1992).
5. For examles: L. Brassard, M. Ribault, L. Valade, and P. Cassoux, Phys. Rev. B, 42, 3935 (1990); H. Kobayashi, K. Bun, T. Naito, R. Kalo, and A. Kobayashi, Chern. Lett., 1909 (1992); H. Tajima, M. Inokuchi, A. Kobayashi, T. Ohta, R. Kalo, H. Kobayashi, and H. Kuroda, Chem. Lett., 1235 (1993).
6. For examles: L. Brassard, M. Ribault, L. Valade, and P. Cassoux, Phys. Rev. B, 42, 3935 (1990); H. Kobayashi, K. Bun, T. Naito, R. Kalo, and A. Kobayashi, Chern. Lett., 1909 (1992); H. Tajima, M. Inokuchi, A. Kobayashi, T. Ohta, R. Kalo, H. Kobayashi, and H. Kuroda, Chem. Lett., 1235 (1993).
7. For examles: L. Brassard, M. Ribault, L. Valade, and P. Cassoux, Phys. Rev. B, 42, 3935 (1990); H. Kobayashi, K. Bun, T. Naito, R. Kalo, and A. Kobayashi, Chern. Lett., 1909 (1992); H. Tajima, M. Inokuchi, A. Kobayashi, T. Ohta, R. Kalo, H. Kobayashi, and H. Kuroda, Chem. Lett., 1235 (1993).
8. R. C. Hadden, Acc. Chem. Res., 25, 127 (1992).
9. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
10. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
11. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
12. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
13. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
14. Y. Misaki, et al., Chem. Lett., 2321 (1992); 729, 1337, 2073 (1993); J. Chem. Soc., Chem. Commun., 459 (1994); T. Mori, et al, Chem. Lett., 733, 2085 (1993); 549 (1995); Bull. Chem. Soc. Jpn., 67, 661, 3187 (1994).
15. Y. Misaki, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, Chem. Lett., 1653 (1994); T. Mori, Y. Misaki, H. Fujiwara, and T. Yamabe, Bull. Chem. Soc. Jpn. 62, 2685 (1994).
16. Y. Misaki, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, Chem. Lett., 1653 (1994); T. Mori, Y. Misaki, H. Fujiwara, and T. Yamabe, Bull. Chem. Soc. Jpn. 62, 2685 (1994).
17. For examples: Y. Yamashita, Y. Kobayashi, and T. Miyashi, Angew. Chem. Int. Ed. Engl., 21, 1052 (1989); K. Takahashi, T. Nihira, and K. Tomitani, J. Chem. Soc. Chem. Commun., 1617 (1993); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. E. Niziurski-Mann, F. Jensen, and J. Becher, J. Am. Chem. Soc., 114. 5035 (1992); A. S. Benahmed-Gasmi, P. Frère, B. Garrigues, A. Gorgues, M. Jubault, R. Carlier, and F. Texier, Tetrahedron Lett., 33, 6457 (1992).
18. For examples: Y. Yamashita, Y. Kobayashi, and T. Miyashi, Angew. Chem. Int. Ed. Engl., 21, 1052 (1989); K. Takahashi, T. Nihira, and K. Tomitani, J. Chem. Soc. Chem. Commun., 1617 (1993); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. E. Niziurski-Mann, F. Jensen, and J. Becher, J. Am. Chem. Soc., 114. 5035 (1992); A. S. Benahmed-Gasmi, P. Frère, B. Garrigues, A. Gorgues, M. Jubault, R. Carlier, and F. Texier, Tetrahedron Lett., 33, 6457 (1992).
19. For examples: Y. Yamashita, Y. Kobayashi, and T. Miyashi, Angew. Chem. Int. Ed. Engl., 21, 1052 (1989); K. Takahashi, T. Nihira, and K. Tomitani, J. Chem. Soc. Chem. Commun., 1617 (1993); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. E. Niziurski-Mann, F. Jensen, and J. Becher, J. Am. Chem. Soc., 114. 5035 (1992); A. S. Benahmed-Gasmi, P. Frère, B. Garrigues, A. Gorgues, M. Jubault, R. Carlier, and F. Texier, Tetrahedron Lett., 33, 6457 (1992).
20. For examples: Y. Yamashita, Y. Kobayashi, and T. Miyashi, Angew. Chem. Int. Ed. Engl., 21, 1052 (1989); K. Takahashi, T. Nihira, and K. Tomitani, J. Chem. Soc. Chem. Commun., 1617 (1993); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. E. Niziurski-Mann, F. Jensen, and J. Becher, J. Am. Chem. Soc., 114. 5035 (1992); A. S. Benahmed-Gasmi, P. Frère, B. Garrigues, A. Gorgues, M. Jubault, R. Carlier, and F. Texier, Tetrahedron Lett., 33, 6457 (1992).
21. Z. Yoshida, T. Kawase, H. Awaji, I. Sugimoto, T. Sugimoto, and S. Yoneda, Tetrahedron Lett., 24, 3469 (1983); T. Sugimoto, H. Awaji, I. Sugimoto, Y. Misaki, T. Kawase, S. Yoneda, Z. Yoshida, T. Kobayashi, and H. Anzai, Chem. Mater., 1, 535 (1989); A. J. Moore, M. R. Bryce, D. J. Ando, and M. B. Hursthouse, J. Chem. Soc. Chem. Commun., 320 (1991); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. M. Metzger, and J. Becher, J. Org. Chem., 56, 2720 (1991).
22. Z. Yoshida, T. Kawase, H. Awaji, I. Sugimoto, T. Sugimoto, and S. Yoneda, Tetrahedron Lett., 24, 3469 (1983); T. Sugimoto, H. Awaji, I. Sugimoto, Y. Misaki, T. Kawase, S. Yoneda, Z. Yoshida, T. Kobayashi, and H. Anzai, Chem. Mater., 1, 535 (1989); A. J. Moore, M. R. Bryce, D. J. Ando, and M. B. Hursthouse, J. Chem. Soc. Chem. Commun., 320 (1991); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. M. Metzger, and J. Becher, J. Org. Chem., 56, 2720 (1991).
23. Z. Yoshida, T. Kawase, H. Awaji, I. Sugimoto, T. Sugimoto, and S. Yoneda, Tetrahedron Lett., 24, 3469 (1983); T. Sugimoto, H. Awaji, I. Sugimoto, Y. Misaki, T. Kawase, S. Yoneda, Z. Yoshida, T. Kobayashi, and H. Anzai, Chem. Mater., 1, 535 (1989); A. J. Moore, M. R. Bryce, D. J. Ando, and M. B. Hursthouse, J. Chem. Soc. Chem. Commun., 320 (1991); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. M. Metzger, and J. Becher, J. Org. Chem., 56, 2720 (1991).
24. Z. Yoshida, T. Kawase, H. Awaji, I. Sugimoto, T. Sugimoto, and S. Yoneda, Tetrahedron Lett., 24, 3469 (1983); T. Sugimoto, H. Awaji, I. Sugimoto, Y. Misaki, T. Kawase, S. Yoneda, Z. Yoshida, T. Kobayashi, and H. Anzai, Chem. Mater., 1, 535 (1989); A. J. Moore, M. R. Bryce, D. J. Ando, and M. B. Hursthouse, J. Chem. Soc. Chem. Commun., 320 (1991); T. K. Hansen, M. V. Lakshmikantham, M. P. Cava, R. M. Metzger, and J. Becher, J. Org. Chem., 56, 2720 (1991).
25. Y. Misaki, N. Higuchi, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, Angew. Chem., Int., Ed. Engl., 34, 1222(1995)
26. Y. Misaki, H. Nishikawa, K. Kawakami, T. Uehara, and T. Yamabe, Tetrahedron, Lett., 33, 4321 (1992).
27. Y. Misaki, T. Ohta, N. Higuchi, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, J. Mater. Chem. 5, 1571 (1995); Y. Misaki, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, J. Chem. Soc. Chem. Commun., in press.
28. Y. Misaki, T. Ohta, N. Higuchi, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, J. Mater. Chem. 5, 1571 (1995); Y. Misaki, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, J. Chem. Soc. Chem. Commun., in press.
29. o).
30. -3.
31. K. Kikuchi, I. Ikemoto, and K. Kobayashi, Synth. Met., 19, 551 (1987).
32. G. C. Papavassiliou, G. A. Mousdis, J. S. Zambounis, A. Terzis, A. Hountas, B. Hilti, C. W. Mayer, and J. Pfeiffer, Synth. Met., 27, B379 (1988).
33. R. Kato, H. Kobayashi, and A. Kobayashi, Chem. Lett., 781 (1989).
34. -3, Unfortunately the R value (0.114) is still considerably large owing to the poor quality of the crystal.
35. Y. Misaki, K. Kawakami, H. Fujiwara, T. Yamabe, T. Mori, H. Mori, and S. Tanaka, Chem. Lett., in press.