Absolute kinetics of aminium radical reactions with olefins in acetonitrile solution

Journal of the American Chemical Society

Volumn 118, Issue 1, 1996, Pages 13-19

  Wagner, Brian D ^a   Ruel, Géraldine ^a   Lusztyk, Janusz ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002102255     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja950133y     Document Type: Article

References (51)

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35. Other less thoroughly examined N-nitrosamines studied included di-n-propylnitrosamine. 1-nitrosopytrolidine, and n-propyl-n-butylnitrosamine which upon 266 nm LFP of 0.05 M maleic acid/acetonitrile solutions gave transient absorptions very similar to those shown in Figure 1a.b with aminium radicals lifetimes of 2.3. 2.6, and 1.8 μs, respectively.
36. It has to be noted, however, that the spectra of the aminyl radicals 3b and 4b observed upon photolysis of the nitrosamines 3a and 4a (numbering system given in Table 1 and illustrated in Scheme 1) in the absence of acid (vide infra) were also unaffected by the presence of oxygen.
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41. 33
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