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Volumn 483, Issue 1-2, 1994, Pages 61-71

Schiff bases derived from benzoylferrocene and their cyclopalladated derivatives. X-Ray crystal structure of [P d{(η5-C5H5) Fe[(η5-C5H3)C(C6H5)NC6H5]} Cl(PPh3)]

Author keywords

Cyclopalladation; Ferrocene; Iron; Palladium; Schiff bases; X ray structure

Indexed keywords


EID: 0002091276     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(94)87148-5     Document Type: Article
Times cited : (61)

References (56)
  • 6
    • 77749235787 scopus 로고
    • Cyclopalladated Complexes in Organic Synthesis
    • (1985) Synthesis , pp. 233
    • Ryabov1
  • 38
    • 84912990519 scopus 로고    scopus 로고
    • 3 in a hood at 250°C for 24 h. After this period the sample was transferred to an oven at 130°C to avoid rehydration.
  • 43
    • 84912988568 scopus 로고    scopus 로고
    • The equation of the plane defined by Pd, P, Cl, N C(6) atoms is: (0.9649)XO+(−0.0540)YO+(−0.2572)ZO = 4.2048.
  • 45
    • 84912956678 scopus 로고    scopus 로고
    • The equation of the plane defined by the atoms involved in the five-membered metallacycle is: (0.9772)XO+(−0.0382)YO+ (−0.2082)ZO=4.3677. Max. deviations are found for C(6): −0.017 and N: −0.015 Å.
  • 46
    • 84912975068 scopus 로고    scopus 로고
    • The equation of the plane defined by C(6), C(7), C(8), C(9) and C(10) atoms is: (0.9881)XO+(−0.0577)YO+(−0.1423)ZO = 4.6394. Max. deviations are found for C(6) and C(10) (−0.008 and + 0.007 Å, Respectively)
  • 47
    • 84912997724 scopus 로고    scopus 로고
    • Least-squares plane defined by C(1), C(2), C(3), C(4) and C(5) is: (0.9772)XO + (−0.0502)YO + (−0.2065)ZO = 1.0473. Max. deviations were found for C(1): + 0.011 and C(2): −0.010 Å.
  • 48
    • 84912999406 scopus 로고    scopus 로고
    • The twist angle was calculated according to the definition given by G.P. Palenik and T.J. Giordano, Inorg. Chem. 9 (1970) 2424
  • 49
    • 84913008962 scopus 로고    scopus 로고
    • The equation of the plane defined by C(12), C(13), C(14), C(15), C(16) and C(17) atoms is: (0.2386)XO + (0.9711)YO + (0.026)ZO =0.4833. Max. deviations correspond to C(12): −0.005 and C(13): +0.004 Å.
  • 50
    • 84912979227 scopus 로고    scopus 로고
    • The least squares plane defined by C(18), C 19, C(20), C(21), C(22) and C(23) is: (−0.2242)XO+(−0.4613)YO+(0.8584)ZO =0.9267. Max. deviations were found for C(22): 0.014 and C(21): −0.016 Å.
  • 54
    • 84912973040 scopus 로고    scopus 로고
    • G.M. Sheldrick, Acta Cryst. Sect. A, in press


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.