Vibration-rotation tunneling spectra of the water pentamer: Structure and dynamics

Science

Volumn 271, Issue 5245, 1996, Pages 62-64

  Liu, K ^a   Brown, M G ^a   Cruzan, J D ^a   Saykally, R J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002076419     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.271.5245.62     Document Type: Article

References (36)

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26. To investigate the possibility Of having buffer gas atoms in the observed cluster signal, we used several different noble gases (Ar, He, and a mixture of 70% Ne with He) as the supersonic expansion carrier gas. In all cases, identical absorption signals were observed without any frequency shift; a rare gascontaining cluster with the same water chromophore would have exhibited a significant frequency shift on substitution of the rare gas component
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36. Supported by the Experimental Physical Chemistry Program of the National Science Foundation (CHE-9424482) We thank J G. Loeser and M. J Elrod for enlightening discussions.