Dirhodium(II) carboxylates as building blocks. Macrocyclic dimers with vertically stacked Rh24+ units

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 23, 2000, Pages 4244-4246

  Bonar Law, Richard P ^a   Bickley, Jamie F ^a   Femoni, Cristina ^a   Steiner, Alexander ^a  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002070463     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b007625m     Document Type: Article

References (18)

1. F. A. Cotton and R. A. Walton, Multiple Bonds between Metal Atoms, Clarendon Press, Oxford, 1993, p. 431;
2. F. H. Jardine and P. S. Sheridan, Coord. C/iem. Rev., 1987, 50, 109.
3. C. J. Jones, Chem. Soc. Rev., 1998, 27, 289;
4. Comprehensive Suprainoleciilar Chemistry, eds. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Pergamon, Oxford, 1996, vol. 9, in particular chapters 2, 5, 6 and 7.3;
5. M. Fujita, Chem. Soc. Rev., 1998, 27, 417;
6. B. Olenyuk, A. Fechtenkotter and P. J. Stang, J. Client. Soc., Dalton Trans., 1998, 1707.
7. F. A. Cotton, L. M. Daniels, C. Lin and C. A. Murillo, J. Am. Chem. Soc., 1999, 121, 4538.
8. R. P. Bonar-Law, T. D. McGrath, N. Singh, J. F. Bickley and A. Steiner, Chem. Commun., 1999, 2457.
9. R. H. Cayton, M. H. Chisholm, J. C. Huffman and E. B. Lobkovsky, J. Am. Chem. Soc., 1991, 113, 8709;
10. M. H. Chisholm, Ace. Chem. Res., 2000, 33, 53.
11. Complex 4 exchanges between its two equivalent offset forms on heating; details of this and axial co-ordination to singly and doubly bridged complexes will be reported elsewhere. R. P. Bonar-Law and N. Sinah, unpublished results.
12. For complex 6, Rh(l)-Rh(2) 2.366 A and Rh(3)-Rh(4) 2.371 A (where Rh(l) is the upper atom as drawn in Fig. 1), Rh(lHXTHF) 2.302, Rh(4}-O(THF) 2.315, Rh(2) O 2.248 A, and Rh(3) O 2.286 A. Complex 7 is centrosymmetric with Rh(l)-Rh(2) 2.367, Rh-O(THF) 2.284, and Rh(2) O 2.268 A.
13. (a) D. V. Baxter, R. H. Cayton, M. H. Chisholm, J. C. Huddman, ' E. F. Putilina, S. L. Tage, J. L. Wesemann, J. W. Zwanziger and F. D. Darrington, J. Am. Chem. Soc., 1994, 116, 4551;
14. (b) A.-M. Giroud-Oodquin, J.-C. Marchon, D. Guillon and A. Skoulios, J. Phys. Chem., 1986, 90, 5502.
15. F. A. Cotton, E. V. Dikarev and S.-E. Stiriba, Inorg. Chem., 1999, 38, 4877.
16. F. A. Cotton, E. V. Dikarev and X. Feng, Inorg. Chim. Acta, 1995, 237, 19 and references therein.
17. G. M. Sheldrick, SHELX 97, Program for Crystal Structure Solution and Refinement, University of Göttingen, 1997.
18. CERIUS 2, Molecular Simulations Inc., San Diego, 1997.