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Volumn 133, Issue 1, 1996, Pages 59-64

Thermoneutral nucleophilic substitution of β-distonic ions CH2CH2XH+ in the gas phase (X = OH, OCH3, OC2H5, NH2)

Author keywords

Distonic ions; Gas phase ion molecule reactions; Mass spectrometry ft ion cyclotron resonance; Nucleophilic substitution

Indexed keywords


EID: 0002068342     PISSN: 00378968     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (6)

References (32)
  • 3
    • 33746302906 scopus 로고
    • For instance, the Hofmann-Löffler-Freytag reaction, see: a) Wawzonek S, Thelen PJ, J Am Chem Soc (1950) 72, 2118
    • (1950) J Am Chem Soc , vol.72 , pp. 2118
    • Wawzonek, S.1    Thelen, P.J.2
  • 15
    • 33746300150 scopus 로고
    • Thèse, Université Paris XI
    • a) Leblanc D, Thèse, Université Paris XI (1990)
    • (1990)
    • Leblanc, D.1
  • 27
    • 33746317178 scopus 로고    scopus 로고
    • A detailed study of the different bimolecular reactions of these four /î-distonic ions will be published elsewhere
    • A detailed study of the different bimolecular reactions of these four /î-distonic ions will be published elsewhere.
  • 30
    • 0001599772 scopus 로고
    • co is defined as the efficiency of the reaction. However, in this case, the transition state is symmetric and so maximum efficiency is reached when fcexp/coii = 0.5. The theoretical capture rate constant is derived from the average dipole orientation (ADO) theory, and was determined according to Su T and Chesnavitch WJ, J Chem Phys (1982) 76, 5183.
    • (1982) J Chem Phys , vol.76 , pp. 5183
    • Su, T.1    Chesnavitch, W.J.2
  • 31
    • 33746269509 scopus 로고    scopus 로고
    • note
    • Nevertheless, the reaction of ND3 with "CrkCrhNHj 4 shows that hydrogen exchange occurs one by one between ammonia and the NHs group of the distonic ion. No other reaction is observed [17].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.