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A detailed study of the different bimolecular reactions of these four /î-distonic ions will be published elsewhere
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A detailed study of the different bimolecular reactions of these four /î-distonic ions will be published elsewhere.
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co is defined as the efficiency of the reaction. However, in this case, the transition state is symmetric and so maximum efficiency is reached when fcexp/coii = 0.5. The theoretical capture rate constant is derived from the average dipole orientation (ADO) theory, and was determined according to Su T and Chesnavitch WJ, J Chem Phys (1982) 76, 5183.
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33746269509
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note
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Nevertheless, the reaction of ND3 with "CrkCrhNHj 4 shows that hydrogen exchange occurs one by one between ammonia and the NHs group of the distonic ion. No other reaction is observed [17].
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