Asymmetric aldol reaction of 2-cyanopropionates catalysed by trans-chelating chiral diphosphine ligand TRAP-rhodium(I) complex

Chemical Communications

Volumn , Issue 1, 1998, Pages 71-72

  Kuwano, Ryoichi ^a   Miyazaki, Hiroshi ^a   Ito, Yoshihiko ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002062967     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a706662g     Document Type: Article

References (12)

1. For a review of catalytic asymmetric aldol reactions, see M. Sawamura and Y. Ito, in Catalytic Asymmetric Synthesis, ed. I. Ojima, VCH, New York, 1993, p. 367.
2. T. Naota, H. Taki, M. Mizuno and S.-I. Murahashi, J. Am. Chem. Soc., 1989, 111, 5954;
3. S.-I. Murahashi, T. Naota, H. Taki, M. Mizuno, U. Takaya, S. Komiya, Y. Mizuho, N. Oyasato, M. Hiraoka, M. Hirano and A. Fukuoka, J. Am. Chem. Soc., 1995, 117, 12 436;
4. S. Paganelli, A. Schionato and C. Botteghi, Tetrahedron Lett., 1991, 32, 2807;
5. H. Nemoto, Y. Kubota and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1994, 1665.
6. TRAP = (R,R)-2,2″-Bis[(S)-1-(dialkylphosphino)ethyl]-1,1″-biferrocene: M. Sawamura, H. Hamashima and Y. Ito, Tetrahedron: Asymmetry, 1991, 2, 593;
7. M. Sawamura, H. Hamashima, M. Sugawara, R. Kuwano and Y. Ito, Organometallics, 1995, 14, 4549.
8. M. Sawamura, H. Hahashima and Y. Ito, J. Am. Chem. Soc., 1992, 114, 8295;
9. Tetrahedron, 1994, 50, 4439;
10. M. Sawamura, H. Hamashima, H. Shinoto and Y. Ito, Tetrahedron Lett., 1995, 36, 6479.
11. K. Inagaki, K. Nozaki and H. Takaya, Synlett, 1997, 119.
12. Asymmetric allylic alkylation with TRAP-Rh-Pd catalyst system, see M. Sawamura, M. Sudoh and Y. Ito, J. Am. Chem. Soc., 1996, 118, 3309.