A new apparatus to measure the vapour-liquid equilibria of low-volatility compounds with near-critical carbon dioxide. Experimental and modelling results for carbon dioxide + n-butanol, + 2-butanol, + 2-butyl acetate and + vinyl acetate systems

Journal of Supercritical Fluids

Volumn 11, Issue 1-2, 1997, Pages 1-14

  Stevens, R M M ^a   Shen, X M ^a   De Loos, Th W ^a   De Swaan Arons, J ^a  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Alkanols; Equations of state; Esters; Experimental method; Solubility data; Supercritical carbon dioxide

Indexed keywords

EID: 0002058345     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0896-8446(97)00032-6     Document Type: Article

References (40)

1. 2. Design and performance of solubility equipment and a SCF Reactor, Ph.D. dissertation, Delft University of Technology, Delft, 1994.
2. R. Dohrn, G. Brunner, High-pressure fluid-phase equilibria: Experimental methods and systems investigated (1988-1993), Fluid Phase Equilibria 106 (1995) 213-282.
3. Y. Chisti, M. Moo-Young, Improve the performance of airlift reactors, Chem. Engng Progress June (1993) 38-45.
4. R.A. Bello, C.W. Robinson, M. Moo-Young, Liquid circulation and mixing characteristics of airlift contactors, Can. J. Chem. Engng 62 (1984) 573-577.
5. K. Ishihara, A. Tsukajima, H. Tanaka, M. Kato, T. Sako, M. Sata, T. Hakuta, Vapour-liquid equilibrium for carbon dioxide + 1-butanol at high pressure, J. Chem. Engng Data 41 (1996) 324-325.
6. C. Borch-Jensen, A. Staby, J. Mollerup, Mutual solubility of 1-butanol and carbon dioxide, ethene, ethane, or propane at a reduced supercritical solvent temperature of 1.03, J. Supercritical Fluids 7 (1994) 231-244.
7. D.W. Jennings, R.-J. Lee, A.S. Teja, Vapour-liquid equilibria in the carbon dioxide + ethanol and carbon dioxide + 1-butanol systems, J. Chem. Engng Data 36 (1991) 303-307.
8. D.W. Jennings, M.T. Gude, A.S. Teja, High-pressure vapour-liquid equilibria in carbon dioxide and 1-alkanol mixtures, in: E. Kiran, J. Brennecke (Eds.), Supercritical Fluid Engineering Science, Washington, DC, 1993, pp. 10-33.
9. T. Suzuki, N. Tsuge, K. Nagahama, Solubilities of ethanol, 1-propanol, 2-propanol and 1-butanol in supercritical carbon dioxide at 313 K and 333 K, Fluid Phase Equilibria 67 (1991) 213-226.
10. M.B. King, D.A. Alderson, F.H. Hallah, D.M. Kassim, K.M. Kassim, J.R. Sheldon, R.S. Mahmud, Some vapour/liquid and vapour/solid equilibrium measurements of relevance for supercritical extraction operations, and their correlation, in: M.E. Paulaitis, J.M.L. Penninger, R.D. Gray Jr, P. Davidson (Eds.), Chemical Engineering at Supercritical Fluid Conditions, Butterworthds, London, 1983, pp. 31-80.
11. J. Pardo, M.C. López, J. Santafé, F.M. Royo, J.S. Urieta, Solubility of gases in butanols. I. Solubilities of nonpolar gases in 1-butanol from 263.15 to 303.15 K at 101.33 kPa partial pressure of gas. Fluid Phase Equilibria 109 (1995) 29-37.
12. 2 systems at low solute concentrations, in: M. McHugh et al. (Eds.), Proceedings of the 2nd International Symposium on Supercritical Fluids, Boston, 1991, pp. 66-69.
13. A. Staby, J. Mollerup, Mutual solubilities of mono-alcohols and carbon dioxide: a review of experimental data, Fluid Phase Equilibria 89 (1993) 351-381.
14. S. Winkler, K. Stephan, Phase equilibria of the quaternary system carbon dioxide-water-acetone-n-butanol, in: M. McHugh (Ed.), Proceedings of the 2nd International Symposium on Supercritical fluids, Boston, 1991, pp. 59-62.
15. M. McHugh, V.J. Krukonis, Supercritical Fluid Extraction. Principles and Practice, 2nd. ed., Butterworth-Heinemann, Boston, 1994.
16. R.M.M. Stevens, A. Bakx, P.R.H. van der Neut, Th.W. de Loos, J. de Swaan Arons, Vapour-liquid equilibria of interest for enzymatic reactions in near-critical carbon dioxide: Experimental and modelling results for the ternary system carbon dioxide + vinyl acetate + 2-butanol, in: K. Arai (Ed.), Proceedings of the 2nd International Symposium on Supercritical Fluids, Sendai, Japan, 1997.
17. R.M.M. Stevens, J.C. van Roermund, M.D. Jager, Th.W. de Loos, J. de Swaan Arons, High-pressure vapour-liquid equilibria in the systems carbon dioxide +2-butanol, +2-butyl acetate, + vinyl acetate and calculations with three EOS methods, Fluid Phase Equilibria, in press.
18. E.R. Shenderei, Y.D. Zelvenskii, F.P. Ivanowskii, The solubility of carbon dioxide in alcohols at low temperatures, Gazov. Prom. 3 (12) (1958) 36-42.
19. H. Takeuchi, M. Fujine, T. Sato, K. Onda, Simultaneous determination of diffusion coefficient and solubility of gas in liquid by a diaphragm cell, J. Chem. Engng Jap. 8 (3) (1975) 252-253.
20. A.W. Francis, Ternary systems of liquid carbon dioxide, J. Phys. Chem. 58 (1954) 1099-1114.
21. Z. Wagner, J. Pavliček, Vapour-liquid equilibrium in the carbon dioxide-ethyl acetate system at high pressure, Fluid Phase Equilibria 97 (1994) 119-126.
22. Z. Wagner, Vapour-liquid equilibrium at high pressure in the system containing carbon dioxide and propyl acetate system. Fluid Phase Equilibria 110 (1995) 175-182.
23. Z. Wagner, Vapour-liquid equilibrium in the carbon dioxide-ethyl propanoate system at pressures from 2 to 9 MPa and temperatures from 303 to 323 K, Fluid Phase Equilibria 112 (1995) 125-129.
24. 2 in vinyl acetate and in a mixture of vinyl acetate and acetic acid, J. Chem. Engng Data 38 (1993) 16-17.
25. R. Stryjek, J.H. Vera, PRSV: An improved Peng-Robinson equation of state for pure compounds and mixtures, Can. J. Chem. Engng 64 (1986) 323-344.
26. D.S.H. Wong, S.I. Sandler, Theoretically correct new mixing rule for cubic equations of state, AIChE J. 38 (1992) 671-680.
27. J. Vidal, Mixing rules and excess properties in cubic equations of state, Chem. Engng Sci. 33 (1978) 787-791.
28. M.L. Michelsen, A method for incorporating excess Gibbs energy models in equations of state. Fluid Phase Equilibria 60 (1990) 47-58.
29. S. Dahl, M.L. Michelsen, High-pressure vapour-liquid equilibria with a UNIFAC-based equation of state, AIChE J. 36 (1990) 1828-1836.
30. I.V. Yakoumis, K. Vlachos, G.M. Kontogeorgis, P. Coutsikos, N.S. Kalospiros, F.N. Kolisis, D.P. Tassios, Application of the LCVM model to systems containing organic compounds and supercritical carbon dioxide, J. Supercritical Fluids 9 (2) (1996) 88-98.
31. C. Boukouvalas, N. Spiliotis, Ph. Coutsikos, N. Tzouvaras, D.P. Tassios, Prediction of vapour-liquid equilibrium with the LCVM model: a linear combination of the Vidai and Michelsen mixing rules coupled with the original UNIFAC and the t-mPR equation of state, Fluid Phase Equilibria 92 (1994) 75-106.
32. M.P.W.M. Rijkers, M. Malais, C.J. Peters, J. de Swaan Arons, Measurements on the phase behaviour of binary hydrocarbon mixtures for modelling the condensation behaviour of natural gas. Part 1. The system methane + decane, , Fluid Phase Equilibria 71 (1992) 143-168.
33. C.L. Young, Experimental methods for studying phase behaviour of mixtures at high temperatures and pressures, Specialist Periodical Reports 2, Chemical Society, London, 1978, pp. 71-104.
34. U.K. Deiters, G.M. Schneider, High pressure phase equilibria: experimental methods, Fluid Phase Equilibria 29 (1986) 145-160.
35. W.R. Adams, J.A. Zollweg, W.B. Street, S.S.H. Rizvi, New apparatus for measurement of supercritical fluid-liquid phase equilibria, AIChE J. 34 (8) (1988) 1387-1391.
36. S. Angus, B. Armstrong, K.M. de Reuck K.M. (Eds.), International Thermodynamic Tables of the Fluid State. Carbon Dioxide, International Union of Pure and Applied Chemistry, Pergamon Press, Oxford, 1976.
37. R.M.M. Stevens, X.M. Shen, Th.W. de Loos, J. de Swaan Arons, A new apparatus for the determination of high pressure VLE in systems with supercritical gases, AIChE Annual Meeting, November, 1996, Chicago, paper 78e.
38. D.-Y. Peng, D.B. Robinson, A new two-constant equation of state, Ind. Engng Chem. Fundam. 15 (1) (1976) 59-64.
39. G. Soave, Equilibrium constants from a modified Redlich-Kwong equation of state, Chem. Engng Sci. 27 (1972) 1197-1203.
40. K. Magoulis, D. Tassios, Thermophysical properties of n-alkanes from C1 to C20 and their prediction for higher ones, Fluid Phase Equilibria 56 (1990) 119-140.