Aqueous speciation of yttrium at temperatures from 25 to 340°C at Psat: An in situ EXAFS study

Chemical Geology

Volumn 151, Issue 1-4, 1998, Pages 29-39

  Ragnarsdottir, K Vala ^a,c   Odkers, Eric H ^b   Sherman, David M ^a   Collins, Clare R ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b CNRS   (France)

^c UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Aqueous speciation; EXAFS; Polyatomic species; REE; Water structure; Yttrium

Indexed keywords

EID: 0002050185     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0009-2541(98)00068-0     Document Type: Article

References (73)

1. 4 as an ionic medium. Bull. Chem. Soc. Jpn. 46, 1720-1723.
2. Aziz, A., Lyle, S.J., 1969. Equilibrium constants for aqueous fluoro complexes of scandium, yttrium, americium(III) and curium(III) by extraction into di-2-ethylhexyl phosphoric acid. J. Inorg. Nucl. Chem. 31, 3471-3480.
3. Baes, C.F., Mesmer, R.E., 1976. The Hydrolysis of Cations Wiley-Interscience.
4. Banks, D.A., Yardley, B.W.D., Campbell, A.R., Jarvis, K.E., 1994. REE composition of an aqueous magmatic fluid: a fluid inclusion study from the Capitan pluton, New Mexico. Chem. Geol. 113, 259-265.
5. Bau, M., Dulski, P., 1995. Comparative study of yttrium and rare-earth element behaviours in fluorine-rich hydrothermal fluids Contrib. Mineral. Petrol. 119, 213-223.
6. Baumann, J.C., 1988. Dysprosium(III)-Fluoreszenz in heisser unter Druck stehender wässriger Lösung. J. Chim. Phys. 85, 541-543.
7. Beall, G.W., Milligan, W.O., Wolcott, H.A., 1977. Structural trends in the lanthanide trioxides. J. Inorg. Nucl. Chem. 39, 65-70.
8. 3+. Ark. Kemi. 22, 253-279.
9. Bilal, B.A., Langer, P., 1987. Complex formation of trace elements in geochemical systems: stability constants of fluoro complexes of the lathanides in a fluorite bearing model system up to 200°C and 1000 bar. Inorg. Chim. Acta 140, 297-298.
10. Binsted N., Campbell, J.W., Gurman, S.J., Stephenson, P.C., 1991. SERC Daresbury Laboratory EXCURV92 Program. Daresbury Laboratory, Warrington, UK.
11. Brown, G.E., Parks, G.A., 1989. Synchrotron-based X-ray absorption studies of cation environments in earth materials Rev. Geophys 27, 519-533.
12. Brown, G.E., 1990. Spectroscopic studies of chemisorption reaction mechanisms at oxide-water interfaces. In: Hochella, M.F., White, A.F. (Eds), Mineral-water interface geochemistry. Reviews in Mineralogy, 23, 309-364.
13. Brown, R.G., 1992. Spectroscopy using synchrotron radiation. Spectro. Eur. 4 (3), 10-20.
14. Cantrell, K.J., Byrne, R.H., 1987. Rare-earth element complexation by carbonate and oxalate ions Geochim. Cosmochim. Acta 51, 597-605.
15. Choppin, G.R., Strazik, W.F., 1965. Complexes of trivaient lanthanide and actinide ions, I. Outer-sphere ion pairs Inorg. Chem. 4, 1250-1254.
16. Choppin, G.R., Unrein, P.J., 1963. Halide complexes of the lanthanide elements. J. Inorg. Nucl. Chem. 25, 387-393.
17. Choppin, G.R., 1976. Factors in the complexation of lanthanides In: Lundin, C.E. (Ed.), Froc. 12th Rare-Earth Res Conf., 1, 130-139.
18. Cobaco, M.I., Marques, M.A., Marques, M.I.D., Bushnellwyne, G., Costa, M.M., Delameida, M.J., Andrade, L.C., 1995. Local order in concentrated aqueous-solutions of yttrium chloride and bromide. J. Phys. Cond. Matter 7, 7409-7418.
19. 3+ in aqueous solution: A neutron scattering first order difference study. J. Chem. Phys. 90, 3254-3260.
20. 3+ cation in solution. Russ. J. Inorg. Chem. 26, 1270-1272.
21. 3. J. Phys. Condens Matter 4, 7679-7690.
22. 3 solubilities(25to 150°C) and La-acetate complexing (25-80°C). Chem. Geol. 151, 361-381.
23. Dent, A.J., Mosselmans, J.F.W., 1992. A guide to EXBACK, EXCALIB and EXCURV92. CLRC Daresbury Laboratory, Warrington.
24. Diakonov, I.I., Ragnarsdottir, K.V., Tagirov, B.R., 1998a. Standard thermodynamic properties and heat capacity equations for rare-earth element hydroxides II. Ce(III)-, Pr-, Sm-, Eu(III)-, Gd-, Tb-, Dy-, Ho-, Er-, Tm-, Yb-, and Y-hydroxides Comparison of thermochemical and solubility data. Chem. Geol. 151, 335-360.
25. 3(s). Radiochim. Acta, in press.
26. Enderby, J.E., 1995. Ion solvation via neutron-scattering. Chem. Soc. Rev. 24, 159-168.
27. Farges, F., Sharps, J.A., Brown, G.E., 1993. Local environment around gold (III) in aqueous chloride solutions an EXAFS spectroscopy study. Geochim. Cosmochim. Acta 57, 1243-1252.
28. Firsching, F.H., Brune, S.N., 1991. Solubility products of the trivaient rare-earth phosphates. J. Chem. Eng. Data 36, 93-95.
29. Firsching, F.H., Mohammadzadel, J., 1986. Solubility products of the rare-earth carbonates J. Chem. Eng. Data 31, 40-42.
30. Gammons, C.H., Wood, S.A., Williams-Jones, A.E., 1996. The aqueous geochemistry of the rare-earth elements and yttrium: VI. Stability of neodymium chloride complexes from 25 to 300°C. Geochim. Cosmochim. Acta 60, 4615-4630.
31. Grenthe, I., Spahiu, K., Eriksen, T., 1992. Analysis of the solubility of yttrium carbonate in aqueous perchlorate media using the Pitzer and Bransted-Guggenheim-Scatchard ion-interaction models J. Chem. Soc. Faraday Trans 88, 1267-1273.
32. Gurman, S.J., Binsted, N., Ross, I., 1984. A rapid, exact curved-wave theory for EXAFS calculations J. Phys. C 17, 143-151.
33. Gurman, S.J., Binsted, N., Ross, I., 1986. A rapid, exact curved-wave theory for EXAFS calculations II. The multiple scattering contributions J. Phys. C 19, 1845-1861.
34. Haas, J., Shock, E.L., Sassani, D., 1995. Rare-earth elements in hydrothermal systems: estimates of standard partial molal thermodynamic properties of aqueous complexes of the REE at high pressures and temperatures Geochim. Cosmochim. Acta 59, 4329-4350.
35. Helz, G.R., Charnock, J.M., Vaughan, D.J., Garner, C.D., 1993. Multinuclearity of aqueous copper and zinc bisulfide complexes an EXAFS investigation. Geochim. Cosmochim. Acta 57, 15-25.
36. Helz, G.R., Tossell, J.A., Charnock, J.M., Pattrick, R.A.D., Vaughan, D.J., Garner, C.D., 1995. Oligomerization in As(III) sulfide solutions theoretical constraints and spectroscopic evidence. Geochim. Cosmochim. Acta 59, 4591-4604.
37. Jamtveit, B., Hervig, R.L., 1994. Constraints on transport and kinetics in hydrothermal systems from zoned garnet crystals. Science 263, 505-508.
38. Johansson, G., Wakita, H., 1985. X-ray investigation of the coordination and complex formation of lanthanoid ions in aqueous perchlorite and selenate solutions. Inorg. Chem. 24, 3047-3052.
39. Johansson, G., Yokoyama, H., Ohtaki, H., 1991. Structure of solvated metal ions in nitrate and chloride solutions of erbium(III) and yttrium(III) in dimethyl solfoxide. J. Solution Chem. 20, 859-874.
40. Lee, H.L., Byrne, R.H., 1992. Examination of comparative rare-earth element complexation behaviour using linear free-energy relationships. Geochim. Cosmochim. Acta 56, 1127-1137.
41. Lee, H.L., Byrne, R.H., 1993. Complexation of trivalent rare-earth elements (Ce, Eu, Gd, Tb, Yb) by carbonate ions Geochim. Cosmochim. Acta 57, 295-302.
42. Lee, P.A., Pendry, J.B., 1975. Theory of extended X-ray absorption fine structure. Phys. Rev. B 11, 2795-2811.
43. Lundquist, R., 1982. Hydrophilic complexes of the actinides I. Carbonates of trivalent americium and europium. Acta Chem. Scand. A 36, 741-750.
44. Marcus, Y., 1988. Ion radii in aqueous solutions. Chem. Rev. 88, 1475-1498.
45. Mariano, A.N., 1989. Economic geology of rare-earth minerals. In: Lipin, B.R., McKay, G.A. (Eds), Geochemistry and mineralogy of rare-earth elements Reviews in Mineralogy, 21, 309-338.
46. 3. J. Phys. Condens Matter 2, 9133-9144.
47. Millero, F.J., 1992. Stability constants for the formation of rare-earth inorganic complexes as a function of ionic strength. Geochim. Cosmochim. Acta 56, 3123-3132.
48. Mironov, V.E., Avramenko, N.I., Koperin, A.A., Blokhin, V.V., Eike, M.Y., Isayev, I.D., 1982. Thermodynamics of the formation reactions of the monochlorite complexes of the rare-earth metals in aqueous solutions. Koord. Khim. 8, 636-638.
49. Mosselmans, J.F.W., Schofield, P.F., Chernock, J.M., Garner, C.D., Pattrick, R.A.D., Vaughan, D.J., 1996. X-ray absorption studies of metal-complexes in aqueous solution at elevated temperatures Chem. Geol. 127, 339-350.
50. Oelkers, E.H., Poitrasson, F., Schott, J., Chenery, S., 1995. An experimental study of the rates and stoichiometry of monazite dissolution. Terra Abstracts 7, 329.
51. Oelkers, E.H., Sherman, D.M., Ragnarsdottir, K.V., Collins, C.R., 1998. An EXAFS study of antimony-bearing aqueous solutions at temperatures from 25 to 300°C. Chem. Geol. 151, 21-27.
52. Paul, A.D., Gallo, L.S., van Camp, J.B., 1961. The fluoride complexing of yttrium(III) in aqueous solution. J. Phys. Chem. 65, 441-443.
53. Pfund, D.M., Darab, J.G., Fulton, J.L., 1994. An XAFS study of strontium ions and krypton in supercritical water. J. Phys. Chem. 98, 13102-13107.
54. Powell, H.K.P., 1974. Entropy titrations: a reassessment of data for the reaction of the sulphate ion with trivalent lanthanoid ions J. Chem. Soc., Dalton Trans 74, 1108-1112.
55. Samson, I.M., Liu, W., Williams-Jones, A.E., 1995a. The nature of orthomagmatic hydrothermal fluids in the Oka carbonatite, Quebec, Canada: evidence from fluid inclusions. Geochim. Cosmochim. Acta 59, 1963-1977.
56. Samson, I.M., Williams-Jones, A.E., Liu, W., 1995b. The chemistry of hydrothermal fluids in carbonatites: Evidence from leachate and SEM-decrepitate analysis of fluid inclusions from Oka, Quebec, Canada. Geochim. Cosmochim. Acta 59, 1979-1989.
57. Sayers, D.E., Bunker, B.A., 1988. Data analysis In: Königsberger, D.C., Prins, R. (Eds) X-ray absorption. Principles, applications, techniques of EXAFS, SEXAFS, and XANES. Chem. Anal. 92, Wiley, pp. 211-253.
58. 2 to 250°C. In: Cuney, M., Cathelineau, M. (Eds), Proc. 4th Internat. Symp. on Hydrothermal Reactions, Inst. Lorrain., 231-233.
59. 3 solutions Min. Mag. 58A, 819-820.
60. Seward, T.M., Henderson, C.M., Charnock, J.M., Dobson, B.R., 1995. The hydration of metal cations in hydrothermal solutions Recent EXAFS results In: Kharaka, Y.K., Chudaev, O.V. (Eds), Water-Rock Interaction-9. Balkema, Rotterdam, 43-46.
61. + in hydrothermal solutions to 350°C. Geochim. Cosmochim. Acta 60, 2273-2282.
62. 4+) in aqueous Cl solutions from 25 to 250°C: an in situ EXAFS study, in prep.
63. Shock, E.L., Oelkers, E.H., Johnson, J.W., Sverjensky, D.A., Helgeson, H.C., 1992. Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures. J. Chem. Soc., Farad. Trans. 88, 803-826.
64. Silber, H.B., 1987. Europium(III) comlexation reactions in water, Inorg. Chim. Acta 139, 33-38.
65. Sinha, S.P., 1976. Structure and bonding in highly coordinated lanthanide complexes. Struct. Bonding (Berlin) 25, 69-149.
66. Smith, R.M., Martell, A.E., 1976. Critical stability constants, 4. Inorganic Complexes. Plenum, New York.
67. Smith, R.M., Martell, A.E., 1989. Critical stability constants, 64. Second Supplement. Plenum, New York.
68. Spahiu, K., 1985. Studies on metal carbonate equilibria: 11. Yttrium(III) carbonate complex formation in aqueous perchlorate media of various ionic strengths Acta Chem. Scand. A 39, 33-45.
69. Usherenko, L.N., Skorik, N.A., 1972. Hydrolysis of rare-earth metal, yttrium, scandium, and thorium ions in water and in water-ethanol mixtures Russ. J. Inorg. Chem. 17, 1533-1535.
70. Walker, J.B., Choppin, G.R., 1967. Thermodynamic parameters of fluoride complexes of the lanthanides Adv. Chem. 71, 127-140.
71. Wells, A.L., 1984. Structural inorganic chemistry. 5th edn., Clarendon, Oxford.
72. Wood, S.A., 1990a. The geochemistry of the rare-earth elements and yttrium: 1. Review of available low-temperature data for inorganic complexes and the inorganic speciation of natural waters Chem. Geol. 82, 159-186.
73. Wood, S.A., 1990b. The geochemistry of the rare-earth elements and yttrium: 2. Theoretical predictions of speciation in hydrothermal solutions to 350°C at saturation water pressure. Chem. Geol. 88, 99-125.