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Actually, other fit functions may be used. We reported the power law fit because it is slightly better than other fits such as exponential or Vogel-Fulcher c18. Moreover the power law fit is consistent with the mean field picture of a power law behavior at a dynamical transition above the static transition
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Actually, other fit functions may be used. We reported the power law fit because it is slightly better than other fits such as exponential or Vogel-Fulcher 18. Moreover the power law fit is consistent with the mean field picture of a power law behavior at a dynamical transition above the static transition.
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85037241363
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Note that the Stokes-Einstein law has a general validity only in the hydrodynamical limit, namely, the size of the diffusive particle must be very large compared with the molecular size of the liquid. Experimentally in normal liquids the SE law is verified even for particle sizes of the order of the molecular size. For this range of particle sizes the SE law must be considered a phenomenological law, which seems to break down near the glass transition. This is also the case for our model where the diffusive particle coincides with the particle fluid
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Note that the Stokes-Einstein law has a general validity only in the hydrodynamical limit, namely, the size of the diffusive particle must be very large compared with the molecular size of the liquid. Experimentally in normal liquids the SE law is verified even for particle sizes of the order of the molecular size. For this range of particle sizes the SE law must be considered a phenomenological law, which seems to break down near the glass transition. This is also the case for our model where the diffusive particle coincides with the particle fluid.
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