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49349121293
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The stability of silirenes has been partly ascribed to some favourable p„-dT overlap between carbon and silicon atoms, see
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The stability of silirenes has been partly ascribed to some favourable p„-dT overlap between carbon and silicon atoms, see: P. R. Jones and D. D. White, J. Organomet. Chem., 1978, 154, C33;
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4
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0000612073
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However, more recent SCF calculations suggest only a weak aromatic character and a weak overlap for these species
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J. C. Barthelat, G. Trinquier, and G. Bertrand, J. Am. Chem. Soc., 1979, 101, 3785. However, more recent SCF calculations suggest only a weak aromatic character and a weak overlap for these species.
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Barthelat, J.C.1
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84926452158
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0000758431
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K. S. Fongers, H. Hogeveen, and R. F. Kingma, Tetrahedron Lett., 1983, 24, 643.
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13
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37049040925
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Similar oxidations with iodine have been carried out on more classical phosphine-molybdenum and tungsten carbonyl complexes, see
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Similar oxidations with iodine have been carried out on more classical phosphine-molybdenum and tungsten carbonyl complexes, see: J. Lewis and R. Whyman, J. Chem. Soc., 1965, 5486;
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J. A. Connor, G. K. McEwen, and C. J. Rix, J. Chem. Soc., Dalton Trans., 1974, 589.
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15
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84986768378
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and references cited therein
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H. Goldwhite, D. Rowsell, L. E. Vertal, M. T. Bowers, M. Ashley Cooper, and S. L. Manatt, Org. Magn. Res., 1983, 21,494 and references cited therein.
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16
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0009515999
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Tertiary amines are known to catalyse the reaction of crude S8 with tertiary phosphines, Without 1-methylimidazole, the reaction of S8 with (3) is too slow and (4) is accompanied by various decomposition products
-
Tertiary amines are known to catalyse the reaction of crude S8 with tertiary phosphines: P. D. Bartlett, E. F. Cox, and R. E. Davis, J. Am. Chem. Soc., 1961, 83, 103. Without 1-methylimidazole, the reaction of S8 with (3) is too slow and (4) is accompanied by various decomposition products.
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