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85033767810
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D = + 33.8 (c = 0.50 in n-heptane).
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22
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85033750731
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note
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-2 mbar (Kugelrohr) to remove the solvent and excess diene 5. Yields are based on the 1-aza-diene 3 used (Table). The unchanged imine 3 can be recovered completely.
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23
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85033753612
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note
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21 or dinuclear species cannot be detected).
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24
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85033763302
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note
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According to control experiments chromatography of a mixture of racemic diene complex and the chiral auxiliary leads to complete separation with no optically active impurities left in the diene product.
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