Photon-, reductant-, and oxidant-induced substitution of a CO Ligand on closo-[Cp*2Fe3S2(CO)3] (Cp* = η5-C5Me5)

Chemistry Letters

Volumn , Issue 6, 1998, Pages 561-562

  Yuki, Masahiro ^a   Mitsui, Toshiaki ^a   Inomata, Shinji ^a   Okazaki, Masaaki ^a   Ogino, Hiroshi ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001938620     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.561     Document Type: Article

References (14)

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4. G. J. Bezems, P. H. Rieger, and S. Visco, J. Chem. Soc., Chem. Commun., 1981, 265; M. D. Brown, D. W. Gillon, G. D. Meakins, and G. H. Whitham, J. Chem. Soc., Chem. Commun., 1982, 442; H. H. Ohst and I. K. Kochi, J. Am. Chem. Soc., 108, 2897 (1986); Y. Koide and C. K. Schauer, Organometallics, 12, 4854 (1993).
5. G. J. Bezems, P. H. Rieger, and S. Visco, J. Chem. Soc., Chem. Commun., 1981, 265; M. D. Brown, D. W. Gillon, G. D. Meakins, and G. H. Whitham, J. Chem. Soc., Chem. Commun., 1982, 442; H. H. Ohst and I. K. Kochi, J. Am. Chem. Soc., 108, 2897 (1986); Y. Koide and C. K. Schauer, Organometallics, 12, 4854 (1993).
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7. M. Akita, "Comprehensive Organometallic Chemistry II", ed by E. W. Abel, F G. A. Stone, and G. Wilkinson, Pergamon Press, Oxford (1995), Vol. 7, Chapt. 4.
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9. 2; C. 58.56; H, 5.53%.
10. A. B. Rives, Y. Xiao-Zeng, and R. F. Fenske, Inorg. Chem., 21, 2286 (1982).
11. THF solution of sodium benzophenone ketyl was prepared by refluxing benzophenone (173 mg, 0.949 mmol) and sodium (100 mg, 4.3 mmol) in THF (20 mL) for 75 min before use.
12. 3 in THF was carried out at room temperature. The TLC analysis revealed that 1 was inert to substitution of CO in THF at room temperature in the absence of reductant.
13. 2: C, 49.77; H, 4.70%.
14. w = 0.091.