Thermochemical behaviour of Pt, Ir, Rh and Ru vs fO2 and fS2 in a basaltic melt. Implications for the differentiation and precipitation of these elements

Mineralogy and Petrology

Volumn 68, Issue 1-3, 2000, Pages 29-62

  Amosse J ^a   Dable P ^b   Allibert, M ^b  

^a UNIV GRENOBLE ALPES   (France)

^b UNIV GRENOBLE ALPES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BASALT; DIFFERENTIATION; IRIDIUM; PLATINUM; PRECIPITATION (CHEMISTRY); RHODIUM; RUTHENIUM; THERMOCHEMISTRY;

EID: 0001920110     PISSN: 09300708     EISSN: None     Source Type: Journal    
DOI: 10.1007/s007100050002     Document Type: Article

References (53)

1. Amossé J (1998) Determination of platinum group elements and gold in geological matrices by inductively coupled plasma-mass spectrometry (ICP-MS) after separation with selenium and tellurium carriers. Geostand Newsletter 22: 93-102
2. 2. Geochim Cosmochim Acta 57: 2395-2398
3. Amossé J, Fischer W, Allibert M, Piboule M (1986) Méthode de dosage de platine, palladium, rhodium et or dans les roches silicatées par spectrophotométrie d'absorption atomique électrothermique. Analysis 14: 26-31
4. Amossé J, Allibert M, Fischer W, Piboule M (1987) Etude de l'influence des fugacités d'oxygène et de soufre sur la différenciation des platinoïdes dans les magmas ultramafiques. - Résultats préliminaires. CR Acad Sci Paris Ser II 304: 1183-1185
5. Amossé J, Allibert M, Fischer W, Piboule M (1990) Experimental study of the solubility of platinum and iridium in mafic silicate melts. Implications for the differentiation of platinum-group elements during magmatic processes. Chem Geol 81: 45-53
6. Amossé J, Allibert M, Ostrosi B, Qoku E, Lleshi B (1992) Comportement géochimique et minéralogie des éléments du groupe du platine (PGE) dans le gisement de Krasta (Albanie). CR Acad Sci 315: 559-564
7. Antonenkova ND, Bozhenov VA, Volkova RM, Kuznetsova MG, Matveeva MP, Marchukova ID, Shashkin VS (1989) Investigation of the platinum contact zone. Izvestiya Akademii Nauk SSSR Metally 4: 188-192
8. Arquetoux P, Fouletier J, Amossé J, Delbove F (1990) Electrical and thermochemical characterisation of synthetic feldspar and plagioclase glasses. Phys Chem Glass 31: 85-92
9. Augé T (1985) Platinum-group mineral inclusions in ophiolite chromitite from the Vourinos complex, Greece. Can Mineral 23: 163-171
10. 2, T P et composition: expérimentation, modélisation, implications métallogéniques et géochimiques. Thèse, Université d'Orléans, France
11. Ballhaus C, Stumpfl E (1986) Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluids inclusions. Contrib Mineral Petrol 94: 193-204
12. Ballhaus C, Ryan CG, Mernagh TP, Green DH (1994) The partitioning of Fe, Ni, Cu, Pt and Au between sulfide, metal, and fluid phase: a pilot study. Geochim Cosmochim Acta 58: 811-826
13. Barin I (1989) Thermochemical data of pure substances VCH, Weinheim
14. Barnes SJ, Naldrett A (1986) Geochemistry of the J.M. Reef of the Stillwater Complex, Minneapolis adit area. II. Silicate mineral chemistry and petrogenesis. J Petrol 27: 791-825
15. Barnes S, Campbell I (1988) Role of late magmatic fluids in Merensky-type platinum deposits: a discussion. Geology 16: 488-491
16. Borisov A, Palme H (1997) Experimental determination of the solubility of platinum in silicate melts. Geochim Cosmochim Acta 61: 4349-4357
17. Borisov A, Palme H, Spettel B (1994) Solubility of palladium in silicate melts: implications for core formation in the earth. Geochim Cosmochim Acta 58: 705-716
18. Boudreau AE, Mathez EA, MacCallum IS (1986) Halogen geochemistry of the Stillwater and Bushveld complexes: evidence for transport of the platinum group elements by chlorine-rich fluids. J Petrol 27: 967-986
19. Capobianco CJ, Drake MJ (1990) Partitioning of ruthenium, rhodium and palladium between spinel and silicate melt and implications for platinum group element fractionation trends. Geochim Cosmochim Acta 54: 869-874
20. Capobianco CJ, Hervig RL, Drake MJ (1994) Experimental on crystal/liquid partitioning of Ru, Rh and Pd for magnetite and hematite solid solutions crystallized from silicate melt. Chem Geol 113: 23-43
21. Dablé P (1996) Etude thermodynamique de la solubilité du platine et du rhodium dans les oxydes liquides. Thesis, I.N.P.G. (Inst Natl Polytech), Grenoble, 172pp
22. Dulac J (1969) Compsés spinelles formés entre l'oxyde de ruthénium RuO2 et les oxydes de certains métaux de transition. Bull Soc Fr Mineral Cristallogr 92: 487-488
23. Eriksson G (1973) Thermodynamics studies of high temperature equilibria. Chem Scripta 4: 193-194
24. Ertel W (1996) Bestimmung des Löslichkeitsverhalten und der Metall-Silicate-Verteilungskoeffizienten der siderophile Elemente (Ni, W, Ir, Pt, Rh und Re) in einer haplobasaltischen Schmelze bei hohen Temperaturen. Dissertation, Bayreuth
25. Fleet ME, Stone WE (1991) Partitioning of platinum-group elements in the Fe-Ni-S system and their fractionation in nature. Geochim Cosmochim Acta 55: 245-253
26. Fleet ME, Crocket JH, Stone WE (1996) Partitioning of platinum-group elements (Os, Ir, Ru, Pt, Pd) and gold between sulfide liquid and basalt melt. Geochim Cosmochim Acta 60: 2397-2412
27. Gammons CH, Bloom MS (1993) Experimental investigations of the hydrothermal geochemistry of Pt and Pd. II. The solubility of PtS and PdS in aqueous sulfide solutions to 300°C. Geochim Cosmochim 57: 2469-2479
28. Garuti G, Oddone M, Torres-Ruiz J (1997) Platinum-group-element distribution in subcontinental mantle: evidence from the Ivrea Zone (Italy) and the Betic-Rifean cordillera (Spain and Morocco). Can J Earth Sci 34: 444-463
29. Haughton DR, Roeder PL, Skinner BJ (1974) Solubility of sulfur in mafic magmas. Econ Geol 69: 451-467
30. Hill R, Roeder P (1974) The crystallisation of spinel from basaltic liquid as a function of oxygen fugacity. J Geol 82: 709-729
31. Hoare JP (1985) In: Standard potential in aqueous solution. Marcel Dekker, New York
32. Johan Z (1986) Chromite deposits in the Massif du Sud ophiolite, New Caledonia: genetic considerations. Theophastus Publications S.A., Athens, pp 311-339
33. Johan Z, Ohnenstetter M, Slansky E, Barron LM, Suppel D (1989) Platinum mineralization in the Alaskan-type intrusive complexes near field, New South Wales, Australia, part 1. Platinum-group minerals in clinopyroxenites of the Kelvin Grove Prospect, Owendale intrusion. Mineral Petrol 40: 289-309
34. Kolonin GR (1998) The model of fractional crystallisation of PGE-bearing sulfide melts: conception, experimental basis and some applications. 8th International Platinum Symposium Abstracts, Rustenburg, June 28-July 3
35. Krutzsch B, Kemmler-Sack S (1983) Sauerstoff-Spinelle mit Ruthenium und Iridium. Mat Res Bull 18: 647-652
36. Li C, Naldrett AJ (1993) Sulfide capacity of magma: a quantitative model and its application to the formation of sulfide ores at Sudbury, Ontario. Econ Geol 88: 1253-1260
37. Li C, Barnes SJ, Makovicky E, Rose-Hansen J, Mackovicky M (1996) Partitioning of nickel, copper, iridium, rhenium, platinum and palladium between monosulfide solid solution and sulfide liquid: effects of composition and temperature. Econ Geol 60: 1231-1238
38. Mackovicky E, Karup-Moller (1995) The system Pd-Fe-Ni-S at 900 and 725°C. Mineral Mag 59: 685-702
39. Maurel C, Maurel P (1984) Etude expérimentale de la distribution du fer ferrique entre spinelle chromifére et bain silicaté basique. Bull Min 107: 25-33
40. Melcher F, Grum W, Simon G, Thalhammer TV, Stumpfl EF (1997) Petrogenesis of the ophiolitic giant chromite deposit of Kempirsai, Kazakhstan: a study of solid and fluid inclusions in chromite. J Petrol 38: 1419-1458
41. Naldrett AJ (1969) A portion of the system Fe-S-O between 900°C and 1,080°C and its application to sulfide ore magmas. J Petrol 10: 171-201
42. Naldrett AJ, von Gruenewaldt G (1989) Association of platinum-group elements with chromitite in layered intrusion and ophiolite complexes. Econ Geol 84: 80-187
43. Nell J, O'Neill (1998) How noble are the platinum group elements? A perspective on the oxide-chemistry of palladium, rhodium, iridium, ruthenium and osmium. 8th International Platinum Symposium, Rustenburg, June 28-July 3
44. Ohnenstetter M, Karaj N, Neziraj A, Johan Z, Cinna A (1991) Le potentiel platinifère des ophiolites: minéralisations en éléments du groupe du platine (PGE) dans les massifs de Tropoja et Bulqiza, Albanie. CR Acad Sci Paris 313: 201-208
45. O'Neill H St C, Nell J (1997) Gibbs free energies of formation of RuO2, IrO2 and OsO2: a high temperature electrochemical and calorimetric study. Geochim Cosmochim Acta 24: 5279-5293
46. O'Neill H St C, Dingwell DB, Borisov A, Spettel B, Palme H (1995) Experimental petrochemistry of some highly siderophile elements at high temperatures, and some implications for core formation and the mantle's history. Chem Geol 120: 255-273
47. Pan P, Wood SA (1994) The solubility of Pt and Pd sulfides and Au metal in bisulfide solutions. I. Results at 200-350°C and at saturated vapor pressure. Mineral Deposita 29: 373-390
48. Saint-Jours C (1988) Thermodynamique des mélanges polyanioniques liquides à base d'oxydes: Modélisation Thermodynamique et Mesures de Capacités en Soufre. Thèse, I.N.P.G. (Inst Natl Polytech), Grenoble
49. Slag Atlas (1981) Verlag Stahleisen M.B.H., Düsseldorf
50. Thalhammer OAR, Prochaska W, Mühlhans HW (1990) Solid inclusions in chrome-spinels and platinum group element concentrations from the Hochgrössen and Kraubath Ultramafic Massifs (Austria). Contrib Mineral Petrol 105: 66-80
51. Tredoux M, Lindsay NM, Davies G, McDonald I (1995) The fractionation of platinum-group elements in magmatic systems, with the suggestion of a novel causal mechanism. S Afr J Geol 98: 157-167
52. Wood SA (1987) Thermodynamic calculations of the volatility of the platinum group elements (PGE): the PGE content of fluids at magmatic temperatures. Geochim Cosmochim Acta 51: 3041-3050
53. Wood SA (1987) Application of a multiphase ore mineral solubility experiment to the separation of base metal and gold mineralization in archean greestone terrains. Econ Geol 82: 1044-1048