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Volumn , Issue 8, 1998, Pages 1087-1094

Cation Stabilities, Electrophilicities, and "Carbene Analogue" Character of Low Coordinate Phosphorus Cations

Author keywords

Carbene homologues; Cation stabilities; Computer Chemistry; Electrophilicity; Phosphenium cations

Indexed keywords

CHEMICAL BONDS; METAL COMPLEXES; ORGANIC COMPOUNDS; PHOSPHORUS;

EID: 0001913680     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199808)1998:8<1087::AID-EJIC1087>3.0.CO;2-3     Document Type: Article
Times cited : (87)

References (45)
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    • A nucleophilic attack of this type is represented by the dimerization of homologous diaminoarsenium cations where the observed formation of intermolecular As⋯N contacts may be rationalized in terms of interaction of the HOMO of one with the LUMO of a second cation; see: N. Burford, T. M. Parks, B. W. Royan, B. Borecka, T. S. Cameron, J. F. Richardson, E. J. Gabe, R. Hynes, J. Am. Chem. Soc. 1992, 114, 8147.
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    • [10]). One should therefore bear in mind that different predictions of the reactivities of phosphenium ions may result when correlation effects are included.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.