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A nucleophilic attack of this type is represented by the dimerization of homologous diaminoarsenium cations where the observed formation of intermolecular As⋯N contacts may be rationalized in terms of interaction of the HOMO of one with the LUMO of a second cation; see: N. Burford, T. M. Parks, B. W. Royan, B. Borecka, T. S. Cameron, J. F. Richardson, E. J. Gabe, R. Hynes, J. Am. Chem. Soc. 1992, 114, 8147.
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85153296842
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[12].
-
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-
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41
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85153328864
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note
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2P-moiety from a value of +1.00 for the free ligand to +0.88 in the complex, thus implying a net transfer of electron density from the metal to the ligand. Further studies of the metal-phosphorus bonding in phosphenium complexes are in progress.
-
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42
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85153311194
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[10]). One should therefore bear in mind that different predictions of the reactivities of phosphenium ions may result when correlation effects are included.
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