Synthesis and crystal structure of new Ru(III)-sulfoxide complexes containing a planar N-ligand: mer,cis-RuCl3(1Me-Im)2(S-DMSO) and [4Et-PyH] [trans-RuCl4(4Et-Py) (S-DMSO)]

Inorganica Chimica Acta

Volumn 253, Issue 1, 1996, Pages 87-90

  Geremia, Silvano ^a   Alessio, Enzo ^b   Todone, Flavia ^b  

^a UNIVERSITÀ POLITECNICA DELLE MARCHE   (Italy)

^b UNIVERSITY OF TRIESTE   (Italy)

Author keywords

Crystal structures; Planar N ligand complexes; Ruthenium complexes; Tumor inhibitor

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; COMPLEXATION; CRYSTAL STRUCTURE; DIHEDRAL ANGLE; DIMETHYL SULFOXIDE; LIGANDS; ORGANIC SOLVENTS; SYNTHESIS (CHEMICAL);

1-METHYLIMIDAZOLE; N LIGANDS; PLANAR LIGANDS; RUTHENIUM COMPLEXES; SULFOXIDE LIGANDS; SYNTHESIS AND CRYSTAL STRUCTURE; TITLE COMPOUNDS; X-RAY STRUCTURE;

RUTHENIUM COMPOUNDS;

EID: 0001885606     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(96)05016-5     Document Type: Article

References (19)

1. B. Rosenberg, L. Van Camp, J.E. Trosko and V.H. Mansour, Nature, 222 (1969) 385.
2. (a) S.J. Berners-Price and P.J. Sadler, in M. Nicolini (ed.), Platinum and Other Metal Coordination Compounds in Cancer Chemotherapy, Martinus Nijhoff, Boston, MA, 1988, p. 527;
3. (b) E.B. Boyar and S.D. Robinson, Coord. Chem., 50 (1983) 109;
4. (c) M.E. Heim, H. Flechtner and B.K. Keppler, Progress in Clinical Biochemistry and Medicine, Vol. 10, Springer, Berlin, 1989, p. 25;
5. (d) P. Kopf-Maier, Progress in Clinical Biochemistry and Medicine, Vol. 10, Springer, Berlin, 1989, p, 151;
6. (e) S.G. Ward and R.C. Taylor, in M.F. Gielen (ed.), Metal-Based Anti-Tumor Drugs, Freund, London, 1988, p. 1.
7. G. Mestroni, E. Alessio, G. Sava, S. Pacor and M. Coluccia, in B.K. Keppler (ed.), Metal Complex in Cancer Chemotherapy, VCH, Weinheim, 1993, p. 159.
8. (a) B.K. Keppler, K.G. Lipponer, B. Stenzel and F. Kratz, in B.K. Keppler (ed.), Metal Complex in Cancer Chemotherapy, VCH, Weinheim, 1993, p. 187;
9. (b) J. Chatlas, R. van Eldik and B.K. Keppler, Inorg. Chim. Acta, 233 (1995) 59.
10. E. Alessio, G. Balducci, A. Lutman, G. Mestroni, M. Calligaris and W.M. Attia, Inorg. Chim. Acta, 203 (1993) 205.
11. W.H. Zachariasen, Acta Crystallogr., 16 (1963) 1139.
12. MolEN, an interactive structure solution procedure, Enraf-Nonius, Delft, Netherlands, 1990.
13. M. Henn, E. Alessio, G. Mestroni, M. Calligaris and W.M. Attia, Inorg. Chim. Acta. 187 (1991) 39.
14. G. Sava, S. Pacor, G. Mestroni and E Alessio, Anti-Cancer Drugs, 3 (1992) 25.
15. M. Calligaris, N. Bresciani-Pahor and R.S. Srivastava, Acta Crystallogr., Sect. C, 49 (1994) 448.
16. M. Calligaris and O. Carugo, Coord. Chem. Rev., 153, (1996) 83.
17. J.D. Orbell, L.G. Marzilli and T.J. Kistenmacher, J. Am. Chem. Soc., 103 (1981) 5126.
18. S.E. Sherman and S.J. Lippard, Chem. Rev., 87 (1987) 1153.
19. L.G. Marzilli, M. Iwamoto, E. Alessio, L. Hansen and M. Calligaris, J. Am. Chem. Soc., 116 (1994) 815.