Electrocatalytic reduction of carbon dioxide by mixed-metal trimetallic complexes of the form {[(bpy)2Ru(BL)]2IrCl2}5+ where bpy = 2,2′-bipyridine and BL = 2,3-bis (2-pyridyl) quinoxaline (dpq) or 2,3-bis (2-pyridyl) benzoquinoxaline (dpb)

Inorganica Chimica Acta

Volumn 253, Issue 1, 1996, Pages 7-13

  Nallas, Girlie Naomi A ^a   Brewer, Karen J ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

Carbon dioxide reduction; Electrocatalysis; Iridium complexes; Ruthenium complexes; Trimetallic complexes

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; CATALYSIS; CATALYST SELECTIVITY; EFFICIENCY; ELECTROCATALYSIS; METAL COMPLEXES; METALS; POLLUTION CONTROL; RUTHENIUM COMPOUNDS;

CARBON DIOXIDE REDUCTION; CONTROLLED POTENTIAL ELECTROLYSIS; COORDINATION ENVIRONMENT; ELECTROCATALYTIC REDUCTION; IRIDIUM COMPLEX; RUTHENIUM COMPLEXES; THERMODYNAMIC POTENTIALS; TRIMETALLIC COMPLEXES;

IRIDIUM COMPOUNDS;

EID: 0001797518     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(96)05103-1     Document Type: Article

References (68)

1. M. Aresta and G. Forti (eds.), Carbon Dioxide as a Source of Carbon, NATO ASI Series, Reidel, Dordrecht, 1987.
2. W.M. Ayers (ed.), Catalytic Activation of Carbon Dioxide, ACS Symposium Series, Vol. 363, American Chemical Society, Washington, DC, 1988.
3. G.C. Chinchen, P.J. Denny, J.R. Jennings, M.S. Spencer and K.C. Waugh, Appl. Catal., 36 (1988) 1.
4. Carbon Dioxide and Climate: a Second Assessment, National Academy Press, Washington, DC, 1982.
5. M.E. Royer, C.R. Acad. Sci., 70 (1870) 731.
6. A. Cohen and S. Jahn, Ber. Dtsch. Chem. Ges., 37 (1904) 2836.
7. R. Ehrenfeld, Ber. Dtsch. Chem. Ges., 38 (1905) 4138.
8. (a) S. Summers, S. Leach and K. Frese, J. Electroanal. Chem., 205 (1986) 219;
9. (b) D.P. Summers and K.W. Frese, Langmuir, 4 (1988) 51.
10. (a) K. Hara, A. Tsuneto, A. Kudo and T. Sakata, J. Electrochem. Soc., 141 (1994) 2097;
11. (b) A. Kudo, S. Nakagawa, A. Tsuneto and T. Sakata, J. Electrochem. Soc., 140 (1993) 1541;
12. (c) S. Nakagawa, A. Kudo, M. Azuma and T. Sakata, J. Electroanal. Chem. Interfacial Electrochem., 308 (1991) 339;
13. (d) M. Azuma, K. Hashimoto, M. Hiramoto, M. Watanabe and T. Sakata, J. Electrochem. Soc., 137 (1990) 1772;
14. (e) A. Katoh, H. Uchida, M. Shibata and M. Watanabe, J. Electrochem. Soc., 141 (1994) 2054.
15. (a) Y. Hori, K. Kikuchi and S. Suzuki, Chem. Lett. (1985) 1695;
16. (b) Y. Hori, A. Murata and R. Takahashi, J. Chem. Soc., Faraday Trans., 85 (1989) 2309;
17. Y. Hori, A. Murata, R. Takahashi and S. Suzuki, J. Chem. Soc., Chem. Commun., (1988) 17.
18. R.L. Cook, R.C. MacDuff and A.F. Sammels, J. Electrochem. Soc., 134 (1987) 1873.
19. D.W. Dewulf and A.J. Bard, Catal. Lett. (1988) 73.
20. R. Kostecki and J. Augustynski, Ber. Bunsen-Ges. Phys. Chem., 98 (1994) 1510.
21. H. Yoshitake, K. Takahasi and K. Ota, J. Chem. Soc., Faraday Trans., 90 (1994) 155.
22. Y. Nakato and T. Mori, Proc. Electrochem. Soc. (Proc. Symp. on Environmental Aspects of Electrochemistry and Photoelectrochemistry), Pennington, NJ, 1993, p. 95.
23. (a) H. Noda, S. Ikeda, Y. Oda, K. Imai, M. Maeda and K. Ito, Bull. Chem. Soc. Jpn., 63 (1990) 2459;
24. (b) H. Noda, S. Ikeda, Y. Oda and K. Ito, Chem. Lett., (1989) 289;
25. S. Ikeda, T. Takagi and K. Ito, Bull. Chem. Soc. Jpn., 60 (1987) 2517.
26. G. Kyriacou and A. Anagnostopoulos, J. Electroanal. Chem., 328 (1992) 233.
27. B.P. Sullivan, K. Krist and H.E. Guard (eds.), Electrochemical and Electrocatalytic Reactions of Carbon Dioxide, Elsevier, Amsterdam, 1993.
28. A. Behr, Carbon Dioxide Activation by Metal Complexes, VCH, New York, 1988.
29. (a) M. Hammouche, D. Lexa, M. Momenteau and J.M. Saveant, J. Am. Chem. Soc., 113 (1991) 8455;
30. (b) C. Amatore and J.M. Saveant, J. Am. Chem. Soc., 103 (1981) 5021.
31. (a) C.P. Kubiak and K.S. Ratliff, Israel J. Chem., 31 (1991) 3;
32. (b) K.S. Ratliff, R.E. Lentz and C.P. Kubiak, Organometallics, 11 (1992) 1986.
33. K. Tominaga, Y. Sasaki, M. Kawai, T. Watanabe and M. Saito, J. Chem. Soc., Chem. Commun., (1993) 629.
34. (a) C.M. Bolinger, B.P. Sullivan, D. Conrad, J.A. Gilbert, N. Story and T.J. Meyer, J. Chem., Soc. Chem. Commun., (1985) 796;
35. (b) C.M. Bolinger, N. Story, B.P. Sullivan and T.J. Meyer, Inorg. Chem., 27 (1988) 4582;
36. (c) M.R.M. Bruce, E. Megehee, B.P. Sullivan, H. Thorp, T.R. O'Toole, A. Downard and T.J. Meyer, Organometallics, 7 (1988) 238;
37. (d) M.R.M. Bruce, E. Megehee, B.P. Sullivan, H.H. Thorp, T.R. O'Toole, A. Downard, J.R. Pugh and T.J. Meyer, Inorg. Chem., 31 (1992) 4864;
38. (e) J.R. Pugh, M.R.M. Bruce, B.P. Sullivan and T.J. Meyer, Inorg. Chem., 30 (1991) 86.
39. Y. Hori, H. Wakebe, T. Tsukamoto and O. Koga, Electrochim. Acta, 39 (1994) 1833.
40. A. Szymaszek and F.P. Pruchnik, J. Organomet. Chem., 376 (1989) 133.
41. (a) K. Ogura, C.T. Migita and T. Nagaoka, J. Mol. Cat., 56 (1989) 276;
42. (b) K. Ogura, C.T. Migita and K. Wadaka, J. Mol. Cat,. 67 (1991) 161;
43. K. Ogura and H. Uchida, J. Chem. Soc., Dalton Trans., (1987) 1377;
44. K. Ogura and M. Takagi, J. Electroanal. Chem., 206 (1986) 209.
45. S. Matsuoka, K. Yamamoto, T. Ogata, M. Kusaba, N. Nakashima, E. Fujita and S. Yanagida, J. Am. Chem. Soc., 115 (1993) 601.
46. (a) H. Ishida, H. Tanaka, K. Tanaka, and T. Tanaka, J. Chem. Soc., Chem. Commun., (1987) 131;
47. (b) H. Ishida, K. Fujiki, T. Ohba, K. Ohkubo, K. Tanaka, T. Terada and T. Tanaka, J. Chem. Soc., Dalton Trans., (1990) 2155.
48. T. Tomohiro, K. Uoto and H. Okuno, J. Chem. Soc., Chem. Commun., (1990) 194.
49. C. Arana, S. Yan, M. Keshavarz-K, K.T. Potts and H.D. Abruna, Inorg. Chem., 31 (1992) 3681.
50. A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482.
51. (a) J.P. Collin and J.P. Sauvage, Coord. Chem. Rev., 93 (1989) 245;
52. (b) M. Beley, J.P. Collin, R. Ruppert and J.P. Sauvage, J. Am. Chem. Soc., 108 (1986) 7461;
53. (c) J.P. Collin, A. Jouaiti and J.P. Sauvage, Inorg. Chem., 27 (1988) 1986;
54. (d) M. Beley, J.P. Collin, R. Ruppert and J.P. Sauvage, J. Chem. Soc., Chem. Commun., (1984) 1315;
55. (e) J.P. Petit, P. Chartier, M. Beley and J.P. Sauvage, New J. Chem., 11 (1987) 751.
56. D.J. Pearce and D. Pletcher, J. Electroanal. Chem., 197 (1986) 317.
57. B. Fisher and R. Eisenberg, J. Am. Chem. Soc., 102 (1980) 7361.
58. F.V. Lovecchio, E.S. Gore and D.H. Busch, J. Am. Chem. Soc., 96 (1974) 3109.
59. J.P. Petit, P. Chartier, M. Beley and J.P. Deville, J. Electroanal. Chem., 269 (1989) 267.
60. A. Breikss and H.D. Abruna, J. Electroanal Chem., 201 (1986) 347.
61. (a) J. Hawecker, J.M. Lehn and R. Ziessel, Helv. Chim. Acta, 69 (1986) 1990;
62. (b) J. Chem. Soc., Chem. Commun., (1984) 328.
63. (a) S.C. Rasmussen, M.M. Richter, E. Yi, H. Place and K.J. Brewer, Inorg. Chem., 29 (1990) 3926;
64. (b) J.S. Bridgewater, L.M. Vogler, S.M. Molnar and K.J. Brewer, Inorg. Chim. Acta, 208 (1993) 179;
65. S.M. Molnar, G.N. Nallas, J.S. Bridgewater and K.J. Brewer, J. Am. Chem. Soc., 116 (1994) 5206.
66. J.J. Kirkland, J. Chromatogr. Sci., 9 (1971) 206.
67. R.E. Majors, Anal. Chem., 44 (1972) 1722.
68. F. Feigl, Spot Tests in Organic Analysis, Elsevier, Amsterdam, 1956.