Coordination chemistry of dimethylgold halides with bidentate phosphorus and arsenic ligands - revisited

Chemische Berichte

Volumn 129, Issue 1, 1996, Pages 77-83

  Paul, Martin ^a   Schmidbaur, Hubert ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

Bidentate arsenic ligands; Bidentate phosphorus ligands; Complexes of; Dimethylgold halides

Indexed keywords

EID: 0001789564     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290116     Document Type: Article

References (54)

1. W. J. Pope, C. S. Gibson, Proc. Chem. Soc. 1970, 23, 245.
2. G. E. Coates, C. Parkin, J. Chem. Soc. 1963, 421.
3. C. F. Shaw. R. S. Tobias, Inorg. Chem. 1973, 12, 965-978.
4. S. Komiya, J. C. Huffmann, J. K. Kochi, Inorg. Chem. 1977, 16, 1253-1255.
5. A. Shiotani, H. Schmidbaur, Chem. Ber. 1971, 104, 2838-2846.
6. S. Hietkamp, D. J. Siufkens, K. Vrieze, J. Organomet. Chem. 1979, 169, 107-113.
7. R. B. Klassen, T. H. Baum, Organometallics 1989, 8, 2477-2489.
8. C. K. Mirabelli, D. T. Hill, L. F. Faucette, F. L. McCabe, G. R. Girard, B. Bryan, B. M. Sutton, J. O'Leary Bartus, S. T. Crooke, R. K. Johnson, J. Med. Chem. 1987, 30, 2181-2190.
9. M. Paul, H. Schmidbaur, Z. Naturforsch.. Part B, 1994, 49, 647-649.
10. H. Schmidbaur, A. Wohlleben, F. Wagner, O. Orama, G. Huttner, Chem. Ber. 1977, 110, 1748.
11. H. Schmidbaur, G. Reber, A. Schier, F. E. Wagner, G. Müller, Inorg. Chim. Acta 1988, 147, 143.
12. H. Schmidbaur, A. Stützer, P. Bissinger, A. Schier, Z. Anorg. Allg. Chem. 1993, 619, 1519.
13. C. F. Shaw, III, J. W. Lundeen, R. S. Tobias, J. Organomet. Chem. 1973, 57, 365-374.
14. A. Tamaka, S. A. Magennis, J. K. Kochi, J. Am. Chem. Soc. 1974, 96, 6140-6148.
15. S. Komiya, T. A. Albright, R. Hoffmann, J. K. Kochi, J. Am. Chem. Soc. 1976, 98, 7255-7265.
16. S. Komiya, J. K. Kochi, J. Am. Chem. Soc. 1976, 98, 7599-7607.
17. S. Komiya, J. C. Huffman, J. K. Kochi, Inorg. Chem. 1977, 16, 2138-2140.
18. Lin-Shu Liou, Chao-Pei Liu, Ju-Chun Wang, Acta Crystallogr., Sect. C (Cr. Str. Comm.) 1994, 50, 538.
19. [19a] H. Schmidbaur, A. Wohlleben, U. Schubert, A. Frank, G. Huttner, Chem. Ber. 1977, 110, 2751.
20. [19b] H. Schmidbaur, G. Müller, R. Herr, J. Riede, Organometallics 1985, 4, 1208-1214.
21. L. C. Porter, M. N. I. Khan, C. King, J. P. Fackler Jr., Acta Crystallogr., Sect. C (Cr. Str. Comm.) 1989, 45, 947.
22. Ju-Chur, Wang, M. N. I. Khan, J. P. Fackler, Jr., Acta Crystallogr., Sect. C (Cr. Str. Comm.) 1989, 45, 1482.
23. M. N. I. Khan, C. King, D. D. Heinrich, J. P. Fackler, Jr., L. C. Porter, Inorg. Chem. 1989, 28, 2150.
24. J. Shain, J. P. Fackler. Jr., Inorg. Chim. Acta 1987, 131, 157.
25. R. Uson, J. Fornies, R. Navarro, M. Tomas, C. Fortuno, J. I. Cebollada, A. J. Welch, Polyhedron 1989, 8, 1045.
26. K. Issleib, D. W. MÜller, Chem. Ber. 1959, 92, 3175.
27. H. Nöth, L. Meinel, Z. Anorg. Allg. Chem. 1967, 349, 225-336.
28. K. Sommer, Z. Anorg. Allg. Chem. 1970, 377, 120-127.
29. Dedicated to Prof. H.-D. Scharf on the occasion of his 65th birthday. - Part I: D. Heller, K. Kortus, R. Selke, Liebigs Ann. 1995, 575-581.
30. The direct use of a solvent complex has been described: C. R. Landis, J. Halpern, J. Am Chem. Soc. 1987, 109, 1746-1754. However, in the case of the seven-membered chelate complexes used in this investigation, this appeared impossible due to their instability.
31. K H. B. Kagan, T. P. Dang, J. Am. Chem. Soc. 1972, 94, 6429-6433.
32. [4a] R Seite, G. Pracejus, H. Pracejus, Symo. Rhodium Homog. Catalysis, Vesprem, 1978, 143-148.
33. [4b] R. Selke, React. Kinet. Catal. Leu. 1979, 10, 135-138.
34. [4c] W. R. Cullen, Y. Sugi, Tetrahedron Lett. 1978, 1635-1636.
35. [4d] R. Jackson, D. J. Thompson, J. Organomet. Chem. 1978, 759, C29-C31.
36. [5a] R. Selke, J. Organomet. Chem. 1989, 370, 241-248.
37. [5b] R. Selke, J. Organomet. Chem. 1989, 370, 249-256.
38. U. Berens. D. Leckel, S. C. Oepen, accepted for publication in J. Org. Chem.
39. [7a] M. P. Anderson, L. H. Pignolet, Inorg. Chem. 1981, 4101-4107.
40. [7b] J. M. Brown, P. A. Chaloner, A. G. Kent, B. A. Murrer, P. N. Nicholson, D. Parker, P. I Sidebottom, J. Organomet. Chem. 1981, 216, 263-276.
41. K.A. Achiwa, J. Am. Chem. Soc. 1976, 98, 8265-8266.
42. [9a] H. W. Krause, H. Foken, H. Pracejus, New J. Chem. 1989, 13, 615-620.
43. [9b] H. W. Krause, unpublished results.
44. 0 = COD + COE, integration is feasible.
45. K. J. Laidler. The chemical kinetics of enzyme action, Oxford Clarendon Press, 1958.
46. K. Madeja, W.-H. Böhmer, D. Heller, Wiss. Zestschr. E.-M.-A.Universität Greifswald, Mathemalisch-Naturwissenschaftliche Reihe 1986, 35, 29-34.
47. D. Heller, unpublished results.
48. 13C-NMR respectively). (The error is less than 2% for a concentration ratio of bisolefin to rhodium = 100).
49. 4 in 40 ml of MeOH 3.37 ml (33.3 mmol) of NBD was added. After stirring for 2 min a dark orange solution was obtained. Removal of the solvent under vacuum yielded the pure NBD complex as revealed by NMR spcctroscopy. Even better is the precipitation of the NBD complex from the methanolic solution by diethyl ether.
50. Reasons for this experimental observation are not yet clear; in addition to the disturbance of the equilibrium by the relative fast hydrogenation of the NBD complex, different formation rates of the bisolefin complexes might be important.
51. L. Ojima, T. Kogure, N. Yoda. J. Org. Chem. 1980, 45, 4728-4739.
52. [18a] R Kadyrov, T. Freier, D. Heller, M. Michalik, R. Selke, J. Chem. Soc., Chem. Commun. 1995, 1745-1746.
53. 13C-enriched substrate-rhodium chelates is on hand; J. M. Brown, private communication, June 1995.