Kinetic study and crystal structure of tetrakis(1,4-thioxane)palladium(II). A comparison between platinum(II) and palladium(II) reactivity

Inorganica Chimica Acta

Volumn 261, Issue 1, 1997, Pages 67-75

  Moullet, Bertrand ^a   Zwahlen, Catherine ^a   Frey, Urban ^a   Gervasio, Giuliana ^b   Merbach, André E ^a  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

^b UNIVERSITY OF TURIN   (Italy)

Author keywords

Crystal structures; Kinetics; Ligand exchange; Palladium complexes; Proton NMR; Thioxane complexes; Variable pressure

Indexed keywords

ACTIVATION ENERGY; CRYSTAL STRUCTURE; ENZYME KINETICS; FREE ENERGY; KINETICS; LIGANDS; PLATINUM COMPOUNDS; RATE CONSTANTS; SULFUR;

FIRST-ORDER RATE CONSTANTS; FREE ENERGY OF ACTIVATIONS; LIGAND EXCHANGES; PALLADIUM COMPLEXES; PROTON NMR; SECOND-ORDER RATE CONSTANTS; TEMPERATURE AND PRESSURES; THIOXANE COMPLEXES;

PALLADIUM COMPOUNDS;

EID: 0001787533     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(96)05581-8     Document Type: Article

References (32)

1. E. Toth, D. Pubanz, S. Vauthey, L. Helm and A.E. Merbach, Chem. Eur. J., 2 (1996) 1607.
2. R.G. Wilkins, Kinetics and Mechanism of Reactions of Transition Metal Complexes, VCH, Weinheim, 1991.
3. U. Frey, A.E. Merbach and D.H. Powell, in J.-J. Delpuech (ed.), Dynamics of Solution and Fluid Mixtures by NMR, Wiley, Chichester, UK, 1995, Ch. 6.
4. U. Frey, S. Elmroth, B. Moullet, L.I. Elding and A.E. Merbach, Inorg. Chem., 30 (1991) 5033.
5. N. Hallinan, V. Besançon, M. Forster, G. Elbaze, Y. Ducommun and A.E. Merbach, Inorg. Chem., 30 (1991) 1112.
6. B. Brønnum, H.S. Johansen and L.H. Skibsted, Acta Chem. Scand., 43 (1989) 975.
7. B. Brønnum, H.S. Johansen and L.H. Skibsted, Inorg. Chem., 31 (1992) 3023.
8. L. Helm, L.I. Elding and A.E. Merbach, Helv. Chim. Acta, 67 (1984) 1453.
9. L. Helm, L.I. Elding and A.E. Merbach, Inorg. Chem., 24 (1985) 1719.
10. C. Ammann, P. Meier and A.E. Merbach, J. Magn. Reson., 46 (1982) 319.
11. U. Frey, L. Helm and A.E. Merbach, High Pressure Res., 2 (1990) 237.
12. F.K. Meyer and A.E. Merbach, J. Phys. E.: Sci. Instrum., 12 (1979) 185.
13. Quantum Chemistry Program Exchange, QCPE Program No. 365 (DNMR5), modified version of L. Helm, Université de Lausanne, 1992.
14. ECHANGE derived from EXCNG; J.J. Delpuech, J. Ducom and V. Michon, Bull. Soc. Chim. Fr., (1971) 1848.
15. A.C.T. North, D.C. Phillips and F.S. Mathews, Acta Crystallogr., Sect. A, 24 (1968) 351.
16. Z. Bugarcic, B. Norén, Å. Oskarsson, C. Stälhandske and L.I. Elding, Acta Chem. Scand., 45 (1991) 361.
17. (a) J.M. Fowler and A. Griffiths, Acta Crystallogr., Sect. B, 34 (1978) 1712.
18. (b) M.M. Olmstead, J.B. Siemak and W.K. Musker, Transition Met. Chem., 7 (1982) 214.
19. (c) M.M. Olmstead, W.K. Musker and R.M. Kessler, Transition Met. Chem., 7 (1982) 140.
20. E.A. Allen, N.P. Johnson, D.T. Rosevear and W. Wilkinson, J. Chem. Soc. A, (1970) 2137.
21. R.G. Pearson, J. Am. Chem. Soc., 85 (1963) 3533.
22. (a) R.S. McEwen and G.A. Sim, J. Chem. Soc. A, (1967) 271.
23. (b) J.C. Barnes, G. Hunter and M.W. Lown, J. Chem. Soc., Dalton Trans., (1977) 458.
24. (c) M. Cannas, G. Carta, D. De Filippo, G. Marongiu and E.F. Trogu, Inorg. Chim. Acta, 10 (1974) 145.
25. B.F.G. Johnson, J. Puga and P.R. Raithby, Acta Crystallogr., Sect. B, 37 (1981) 953.
26. L.I. Elding and Å. Oskarsson, Inorg. Chim. Acta, 130 (1987) 209.
27. E.W. Abel, M. Booth and K.G. Orrel, J. Chem. Soc., Dalton Trans., (1980) 1582.
28. J.C. Barnes, G. Hunter and M.W. Lown, J. Chem. Soc., Dalton Trans., (1976) 1227.
29. R.L. Batstone-Cunningham, H.W. Dodgen, J.P. Hunt and D.M. Roundhill, J. Chem. Soc., Dalton Trans., (1983) 1473.
30. D.L. Hasha, T. Eguchi and J. Jonas, J. Am. Chem. Soc., 104 (1982) 2290.
31. J.J. Pesek and W.R. Mason, Inorg. Chem., 22 (1983) 2958.
32. P. Meakin and J. P Jesson, J. Am. Chem. Soc., 96 (1974) 5751.