A prerequisite for purely organic molecule-based ferrimagnetics: Breakdown of simple classical pictures

Journal of Physical Chemistry B

Volumn 101, Issue 17, 1997, Pages 3342-3348

  Shiomi, Daisuke ^a   Nishizawa, Masahiro ^a   Sato, Kazunobu ^a   Takui, Takeji ^a   Itoh, Koichi ^a   Sakurai, Hiromi ^b   Izuoka, Akira ^b   Sugawara, Tadashi ^b  

^a Osaka Prefecture University   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001764958     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970111t     Document Type: Article

References (25)

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11. We have modified the program package "TITPACK" version 2 supplied by H. Nishimori at Tokyo Institute of Technology.
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20. -1 corresponding to three S = 1/2 spins in a unit cell. The "reentrant" behavior of χT, both a maximum and a minimum in χT, has been observed more clearly in the present measurement than in the previous one in ref 6. The difference in the absolute value of χT in the "reentrant" region might result from the static field value applied in the experiments or the chemical freshness of the sample. The discussion on the susceptibility in this paper is based on the new experimental result shown in Figure 9. The temperature dependence of χT above 30 K is essentially identical with that previously reported.
21. Within the static field range of B < 6 T, no spin flop-like anomaly in the magnetization curve was observed.
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23. For example, see; (a) Kahn, O.; Pei, Y.; Verdaguer, M.; Renard, J. P.; Sletten, J. J. Am. Chem. Soc. 1988, 110, 782. (b) Caneschi, A.; Gateschi, D.; Renard, J. P.; Rey, P.; Sessoli, R. Inorg. Chem. 1989. 28, 1976. (c) Stumpf, H. O.; Ouahab, L.; Pei, Y.; Bergerat, P.; Kahn, O. J. Am. Chem. Soc. 1994, 116, 3866.
24. For example, see; (a) Kahn, O.; Pei, Y.; Verdaguer, M.; Renard, J. P.; Sletten, J. J. Am. Chem. Soc. 1988, 110, 782. (b) Caneschi, A.; Gateschi, D.; Renard, J. P.; Rey, P.; Sessoli, R. Inorg. Chem. 1989. 28, 1976. (c) Stumpf, H. O.; Ouahab, L.; Pei, Y.; Bergerat, P.; Kahn, O. J. Am. Chem. Soc. 1994, 116, 3866.
25. For example, see; (a) Kahn, O.; Pei, Y.; Verdaguer, M.; Renard, J. P.; Sletten, J. J. Am. Chem. Soc. 1988, 110, 782. (b) Caneschi, A.; Gateschi, D.; Renard, J. P.; Rey, P.; Sessoli, R. Inorg. Chem. 1989. 28, 1976. (c) Stumpf, H. O.; Ouahab, L.; Pei, Y.; Bergerat, P.; Kahn, O. J. Am. Chem. Soc. 1994, 116, 3866.