Cyclometalated complexes with triphosphine ligands: A novel route for promoting pentacoordination in palladium(II)

Organometallics

Volumn 18, Issue 26, 1999, Pages 5484-5487

  Vila, José M ^a   Pereira, Ma Teresa ^a   Ortigueira, Juan M ^a   Fernández, Jesús J ^b   Fernández, Alberto ^b   López Torres, Margarita ^b   Adams, Harry ^c  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

^b UNIVERSITY OF A CORUÑA   (Spain)

^c UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001754432     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9906363     Document Type: Article

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27. 3 a triplet and a doublet were observed, as for complex 2, The molecular structure of this compound was determined by X-ray crystallography; the Pd-N distance of 2.438 A is, with the exception of compound 2, the shortest distance so far reported for these compounds (see text), pointing toward a close-to-pentacoordinated complex, as well.
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