Unusual Me - O bond cleavage in a metalated crown-ether: X-ray molecular structure of (5-methoxy-4,6-dimethyl-1,3-xylylene-2-one)-15 crown-4 complex of pentamethylcyclopentadienyl iridium

Inorganic Chemistry

Volumn 38, Issue 6, 1999, Pages 1211-1215

  Amouri, H ^a   Vaissermann, J ^a   Rager, M N ^b   Besace, Y ^b  

^a EUROPEAN SPACE AGENCY   (France)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001748274     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980811s     Document Type: Article

References (13)

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7. Le Bras; J.; Amouri, H.; Vaissermann J. Organometallics 1998, 17, 1116. Le Bras, J.; Amouri, H.; Vaissermann, J. J. Organomet. Chem. 1998, 553, 503.
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11. (d) Lehn, J.-M. Multidentate Macrocyclic and Macropolycyclic Ligands In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 2, pp 915-957.
12. Staffilani, M.; Hancock, K. S. B.; Steed, J. W.; Holman, K. T.; Atwood J. L.; Ravindra, K. J.; Burkhalter, R. S. J. Am. Chem. Soc. 1997, 119, 6324.
13. This compound was prepared by an improved synthetic procedure of the literature method; see: Delgado, M.; Wolf, E. R., Jr.; Hartman, J. R.; McCafferty, G.; Yagbassan, R.; Rawle, S. C.; Watkin, D. J.; Cooper S. R. J. Am. Chem. Soc. 1992, 114, 8983.