메뉴 건너뛰기




Volumn 19, Issue 11, 1980, Pages 883-899

Chemistry of Thiazyl Fluoride (NSF) and Thiazyl Trifluoride (NSF3): A Quarter Century of Sulfur‐Nitrogen‐Fluorine Chemistry

Author keywords

Fluorine; Sulfur nitrogen fluorine compounds; Thiazyl fluorides

Indexed keywords

CHEMICAL REACTIONS; NITROGEN COMPOUNDS - SYNTHESIS;

EID: 0001737412     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198008831     Document Type: Review
Times cited : (94)

References (258)
  • 9
  • 43
    • 0038964044 scopus 로고
    • Umsetzung von Übergangsmetallcarbonylhalogeniden mit AgAsF6 in flüssigem SO2: eine Schlüsselreaktion zur Darstellung neuer Komplex-Kationen
    • (1975) Angewandte Chemie , vol.87 , pp. 669
    • Mews, R.1
  • 45
    • 84985540599 scopus 로고    scopus 로고
    • 5NSCl]⊕ (R. Mews, unpublished).
  • 87
    • 84981819805 scopus 로고
    • N-Fluor-sulfonylfluoridamid,N-Fluor-(pentafluorschwefel)sulfonylfluoridamid undN-Dichlormethylen-carbonylfluoridamid
    • (1968) Angewandte Chemie , vol.80 , pp. 626
    • Roesky, H.W.1
  • 92
    • 84908878524 scopus 로고
    • Über die photochemische Reaktion von FCONSF2 mit OF2 und F2
    • 5SOOC(O)F are formed, along with the products from Reaction (24) and other substances
    • (1977) Chemische Berichte , vol.110 , pp. 2398
    • Stahl, I.1    Mews, R.2    Glemser, O.3
  • 108
  • 123
    • 84985563361 scopus 로고    scopus 로고
    • 3]⊕ [80].
  • 125
    • 84985629298 scopus 로고    scopus 로고
    • 1H‐NMR spectrum a quartet. Below 0°C, complex multiplets appear, which constantly alter up to −120°C. Below 0°C, the transposition of the axial and equatorial atoms is difficult, and rotation around the C—N axis is hindered.
  • 149
    • 84985496345 scopus 로고    scopus 로고
    • 3.
  • 182
    • 84985604135 scopus 로고    scopus 로고
    • 2, the two Mn—N bonds which are “cis” to the F atoms, are shorter (if only a little) than the other two.
  • 195
    • 84985635153 scopus 로고    scopus 로고
    • Sulfur is surrounded by the three ligands so forming a Y; “triene” corresponds to the three double bonds.
  • 211
    • 84985509023 scopus 로고
    • (1966) , vol.5 , pp. 732
  • 216
  • 232
    • 84985600058 scopus 로고    scopus 로고
    • 3 are also practically the same [171].
  • 237
    • 84985587717 scopus 로고    scopus 로고
    • Dissertation, Universität Göttingen 1976. The reaction was followed by using the 19F‐NMR spectrum. cis‐Fluorine gives a singlet, trans‐fluorine an A2B spectrum (cf. [187]).
    • Wagner, H.1
  • 245
    • 84943712702 scopus 로고
    • Über das 3,5-Difluor-1,3,5-trioxo-1λ6, 3λ6, 5λ6, 2,4,6-trithiatriazin-1-olat-Anion und das 3,5-Difluor-3,5-dioxo-1λ4,3λ6,5λ6,2,4,6-tri-thiatriazin-1-olat-Anion
    • (1975) Chemische Berichte , vol.108 , pp. 2469
    • Wagner, D.L.1    Wagner, H.2    Glemser, O.3
  • 246
    • 84985635113 scopus 로고    scopus 로고
    • An analogous anion has not yet been observed with the isoelectronic hexahalocyclotriphosphazenes.
  • 248
    • 84985635112 scopus 로고    scopus 로고
    • FF = 3.75 Hz. The two F atoms are cis.
  • 252
    • 84982480505 scopus 로고
    • Einige Seitenkettenreaktionen des 1-Amino-3,5-difluor-1,3,5-trioxo-1λ6, 3λ6, 5λ6, 2,4,6-trithiatriazin-Ammoniaks (1/1)
    • (1976) Chemische Berichte , vol.109 , pp. 3537
    • Lin, T.P.1    Glemser, O.2
  • 258
    • 84985570243 scopus 로고    scopus 로고
    • 3 has proven to be effective against Fasciola (liver fluke) in vitro, but the compound appears to be toxic; Bayer AG, unpublished.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.