Synthesis and X-ray Crystal Structure Determination of the First Lanthanide Complexes Containing Primary Phosphide Ligands: Ln[P(H)Mes*]2(thf)4 (Ln = Yb, Eu)

Inorganic Chemistry

Volumn 36, Issue 22, 1997, Pages 4914-4915

  Rabe, Gerd W ^a   Guzei, Ilia A ^b   Rheingold, Arnold L ^b  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001714323     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970422i     Document Type: Article

References (22)

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15. -3, was 0.63 Å from the metal and was considered noise. All non-hydrogen atoms were refined with anisotropic displacement coefficients. The hydrogen atom on phosphorus was located, and its thermal parameter was refined while the P-H distance was constrained to 1.400(2) Å. All other hydrogen atoms were treated as idealized contributions. All software and sources of scattering factors are contained in the SHELXTL (5.3) program library (G. Sheldrick, Siemens, XRD, Madison, WI). Atomic coordinates, bond distances and angles, and thermal parameters of 1 and 2 have been deposited at the Cambridge Crystallographic Data Centre (Depository No. CSD-100132).
16. Karsch, H. H.; Ferazin, G.; Steigelmann, O.; Kooijman, H.; Filler, W. Angew. Chem., Int. Ed. Engl. 1993, 32, 1739.
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21. 2: C, 61.64; H, 8.78; P, 8.03. Found: C, 61.93; H, 8.99; P, 7.88.
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