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note
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It may be argued that the stabilization is not due to participation of the β-halo substituent but due to hypcrconjugation. However, our preliminary results with sulfenyl chlorides suggest that the alkyl(aryl)thio group does not stabilize the cation. Because the alkyl(aryl)thio cation must be stable with respect to the halogen cations, we believe the bulkiness together with ionization potentials of halogens is responsible to the stabilization. The results of the reaction of chalcogenyl halides with compound 1 will be a subject of another paper which should be published in due course.
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