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Volumn 70, Issue 4, 1997, Pages 859-868

Reactions of ap- And sp-1-(9-Fluorenyl)-2-(1-methylethenyl)naphthalene Rotamers with Bromine Chloride or Iodine Chloride and Unusual Populations of the Corresponding 1-(9-Fluorenyl)-2-[(E)-2-halo-1-methylethenyl]naphthalene Rotamers

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EID: 0001699125     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.70.859     Document Type: Article
Times cited : (5)

References (33)
  • 11
    • 0002672933 scopus 로고
    • Iodine Monochloride
    • ed by J. S. Pizey John Wiley, New York Chap. 2
    • C. W. McCleland, "Iodine Monochloride," ed by J. S. Pizey. in "Synthetic Reagents," John Wiley, New York (1977), Vol. 3. Chap. 2, pp. 85-164.
    • (1977) Synthetic Reagents , vol.3 , pp. 85-164
    • McCleland, C.W.1
  • 15
  • 30
    • 85033146756 scopus 로고    scopus 로고
    • note
    • It may be argued that the stabilization is not due to participation of the β-halo substituent but due to hypcrconjugation. However, our preliminary results with sulfenyl chlorides suggest that the alkyl(aryl)thio group does not stabilize the cation. Because the alkyl(aryl)thio cation must be stable with respect to the halogen cations, we believe the bulkiness together with ionization potentials of halogens is responsible to the stabilization. The results of the reaction of chalcogenyl halides with compound 1 will be a subject of another paper which should be published in due course.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.