Silicon-based organometallic dendritic macromolecules containing {η6-(organosilyl)arene}chromium tricarbonyl moieties

Journal of Organometallic Chemistry

Volumn 509, Issue 1, 1996, Pages 109-113

  Lobete, Francisco ^a   Cuadrado, Isabel ^a   Casado, Carmen M ^a   Alonso, Beatriz ^a   Morán, Moisés ^a   Losada, José ^b  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

^b UNIVERSIDAD POLITÉCNICA DE MADRID   (Spain)

Author keywords

Chromium; Organometallic dendrimers; Silicon

Indexed keywords

ARENE;

EID: 0001694741     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)06057-4     Document Type: Article

References (24)

1. For recent reviews on dendritic macromolecules see: (a) G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT, Vol. 1, 1994, Vol. 2, 1995 (b) D.A. Tomalia and H.D, Durst, in E. Weber (ed.) Topics in Current Chemistry, Vol. 165, Springer, Berlin, 1993, p. 193 (c) J. Issberner, R. Moors and F. Vögtle, Angew. Chem., Int. Ed. Engl., 33 (1994) 2413 (d) J.M. Fréchet, Science, 263 (1994) 1710 (e) D.A. Tomalia, Adv. Mater., 6 (1994) 529.
2. For recent reviews on dendritic macromolecules see: (a) G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT, Vol. 1, 1994, Vol. 2, 1995 (b) D.A. Tomalia and H.D, Durst, in E. Weber (ed.) Topics in Current Chemistry, Vol. 165, Springer, Berlin, 1993, p. 193 (c) J. Issberner, R. Moors and F. Vögtle, Angew. Chem., Int. Ed. Engl., 33 (1994) 2413 (d) J.M. Fréchet, Science, 263 (1994) 1710 (e) D.A. Tomalia, Adv. Mater., 6 (1994) 529.
3. For recent reviews on dendritic macromolecules see: (a) G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT, Vol. 1, 1994, Vol. 2, 1995 (b) D.A. Tomalia and H.D, Durst, in E. Weber (ed.) Topics in Current Chemistry, Vol. 165, Springer, Berlin, 1993, p. 193 (c) J. Issberner, R. Moors and F. Vögtle, Angew. Chem., Int. Ed. Engl., 33 (1994) 2413 (d) J.M. Fréchet, Science, 263 (1994) 1710 (e) D.A. Tomalia, Adv. Mater., 6 (1994) 529.
4. For recent reviews on dendritic macromolecules see: (a) G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT, Vol. 1, 1994, Vol. 2, 1995 (b) D.A. Tomalia and H.D, Durst, in E. Weber (ed.) Topics in Current Chemistry, Vol. 165, Springer, Berlin, 1993, p. 193 (c) J. Issberner, R. Moors and F. Vögtle, Angew. Chem., Int. Ed. Engl., 33 (1994) 2413 (d) J.M. Fréchet, Science, 263 (1994) 1710 (e) D.A. Tomalia, Adv. Mater., 6 (1994) 529.
5. For recent reviews on dendritic macromolecules see: (a) G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT, Vol. 1, 1994, Vol. 2, 1995 (b) D.A. Tomalia and H.D, Durst, in E. Weber (ed.) Topics in Current Chemistry, Vol. 165, Springer, Berlin, 1993, p. 193 (c) J. Issberner, R. Moors and F. Vögtle, Angew. Chem., Int. Ed. Engl., 33 (1994) 2413 (d) J.M. Fréchet, Science, 263 (1994) 1710 (e) D.A. Tomalia, Adv. Mater., 6 (1994) 529.
6. I. Cuadrado, M. Moŕan, J. Losada, C.M. Casado, C. Pascual, B. Alonso and F. Lobete, in G.R. Newkome (ed.), Advances in Dendritic Macromolecules, JAI, Greenwich, CT., 1996, Vol. 3, in press.
7. For recent works on organometallic dendrimers see for example: (a) J.W.J. Knapen, A.W. van der Made, J.C. de Wilde, P.W.N.M. van Leeuwen, P. Wijkens, D. Grove and G. van Koten, Nature, 372 (1994) 659 (b) A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482 (c) J.L. Fillaut, J. Linares and D. Astruc, Angew. Chem., Int. ed. Engl., 33 (1994) 2460 (d) S. Achar and R.J. Puddephatt, J. Chem. Soc., Chem. Commun., (1994) 1895 (e) Y.H. Liao and J.R. Moss, Organometallics, 14 (1995) 2130.
8. For recent works on organometallic dendrimers see for example: (a) J.W.J. Knapen, A.W. van der Made, J.C. de Wilde, P.W.N.M. van Leeuwen, P. Wijkens, D. Grove and G. van Koten, Nature, 372 (1994) 659 (b) A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482 (c) J.L. Fillaut, J. Linares and D. Astruc, Angew. Chem., Int. ed. Engl., 33 (1994) 2460 (d) S. Achar and R.J. Puddephatt, J. Chem. Soc., Chem. Commun., (1994) 1895 (e) Y.H. Liao and J.R. Moss, Organometallics, 14 (1995) 2130.
9. For recent works on organometallic dendrimers see for example: (a) J.W.J. Knapen, A.W. van der Made, J.C. de Wilde, P.W.N.M. van Leeuwen, P. Wijkens, D. Grove and G. van Koten, Nature, 372 (1994) 659 (b) A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482 (c) J.L. Fillaut, J. Linares and D. Astruc, Angew. Chem., Int. ed. Engl., 33 (1994) 2460 (d) S. Achar and R.J. Puddephatt, J. Chem. Soc., Chem. Commun., (1994) 1895 (e) Y.H. Liao and J.R. Moss, Organometallics, 14 (1995) 2130.
10. For recent works on organometallic dendrimers see for example: (a) J.W.J. Knapen, A.W. van der Made, J.C. de Wilde, P.W.N.M. van Leeuwen, P. Wijkens, D. Grove and G. van Koten, Nature, 372 (1994) 659 (b) A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482 (c) J.L. Fillaut, J. Linares and D. Astruc, Angew. Chem., Int. ed. Engl., 33 (1994) 2460 (d) S. Achar and R.J. Puddephatt, J. Chem. Soc., Chem. Commun., (1994) 1895 (e) Y.H. Liao and J.R. Moss, Organometallics, 14 (1995) 2130.
11. For recent works on organometallic dendrimers see for example: (a) J.W.J. Knapen, A.W. van der Made, J.C. de Wilde, P.W.N.M. van Leeuwen, P. Wijkens, D. Grove and G. van Koten, Nature, 372 (1994) 659 (b) A. Miedaner, C.J. Curtis, R.M. Barkley and D.L. DuBois, Inorg. Chem., 33 (1994) 5482 (c) J.L. Fillaut, J. Linares and D. Astruc, Angew. Chem., Int. ed. Engl., 33 (1994) 2460 (d) S. Achar and R.J. Puddephatt, J. Chem. Soc., Chem. Commun., (1994) 1895 (e) Y.H. Liao and J.R. Moss, Organometallics, 14 (1995) 2130.
12. (a) C.M. Casado, I. Cuadrado, M. Morán, B. Alonso, F. Lobete and J. Losada, Organometallics, 14 (1995) 2618
13. (b) C.M. Casado, M. Morán, J. Losada and I. Cuadrado, Inorg. Chem., 34 (1995) 1668, and references cited therein.
14. B. Alonso, I. Cuadrado, M. Morán and J. Losada, J. Chem. Soc., Chem. Commun., (1994) 2575.
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16. 2 will be reported in the full paper.
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19. A.W. van der Made and P.W.N.M. van Leeuwen, J. Chem. Soc., Chem. Commun., (1992) 1400.
20. 3: C, 64.65; H, 7.86. Found: C, 64.49; H, 7.79.
21. 12: C, 59.77; H, 7.44, Found: C, 59.53; H. 7.39.
22. 6-(organosily)-arene)chromium tricarbonyl mono- and polymetallic compounds: M, Morán, I. Cuadrado, C. Pascual, C.M. Casado, and J. Losada, Organometallics, 11 (1992) 1210.
23. Fox details of the electrochemical and spectroelectrochemical measurements see Ref. [4b].
24. J.B. Flanagan, S. Margel, A.J. Bard and F.C. Anson, J. Am. Chem. Soc., 100 (1978) 4248.