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Volumn 103, Issue 21, 1999, Pages 4293-4297

Four-Electron Three-Center Bonding: One-Electron and Concerted Two-Electron Delocalizations into Bonding and Antibonding Molecular Orbitals

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EID: 0001691807     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9900988     Document Type: Article
Times cited : (26)

References (62)
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    • Maksić, Z. B., Orville-Thomas, W. J., Eds.; Elsevier: New York, see also references therein
    • (c) In Pauling's Legacy-Modern Theory (Modelling) of Chemical Bonding; Maksić, Z. B., Orville-Thomas, W. J., Eds.; Elsevier: New York, 1999; p 449 (see also references therein)
    • (1999) Pauling's Legacy-Modern Theory (Modelling) of Chemical Bonding , pp. 449
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    • and refs 1-13, 15, and 16 therein
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    • Wiley: Chichester, U.K.
    • (e) In Klapötke, T. M.; Schulz, A. Quantum Chemical Methods in Main-Group Chemistry; Wiley: Chichester, U.K., 1998; p 217. Atomic formal charges in the VB structures of the present paper have been assigned on the assumption that the bonding electrons are shared equally by pairs of adjacent atoms. Values for the variationally-best formal charges must be obtained via calculation. In VB structures 2-10 and 14-17, the formal charges displayed are relative to those for structure 1, in which it has been assumed that the Y, A, and B formal charges have values of zero here.
    • (1998) Quantum Chemical Methods in Main-Group Chemistry , pp. 217
    • Klapötke, T.M.1    Schulz, A.2
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    • A selection of additional references from our laboratory includes the following: Harcourt, R. D. (a) Aust. J. Chem. 1969, 22, 279
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    • (c) Ibid. 1971, 9, 221
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    • (d) Ibid. 1972, 12, 351
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    • (e) Aust. J. Chem. 1975, 28, 881
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    • (j) J. Mol. Struct. 1993, 300, 243
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    • (1996) J. Mol. Struct. (Theochem) , vol.369 , pp. 217
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    • Some other references (with no increased-valence structures) by other workers include: (a) Musher, J. L. Angew. Chem., Int. Ed. Engl. 1969, 8, 54.
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    • (c) Salzner, U.; Schleyer, P. v. R. J. Am. Chem. Soc. 1993, 115, 10231. Various types of designations and associated MO descriptions for intermolecular interactions have been summarized by: Bent, H. A. Chem. Rev. 1968, 68, 587.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 10231
    • Salzner, U.1    Schleyer, P.V.R.2
  • 44
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    • Salzner, U.; Schleyer, P. v. R. J. Am. Chem. Soc. 1993, 115, 10231. Various types of designations and associated MO descriptions for intermolecular interactions have been summarized by: Bent, H. A. Chem. Rev. 1968, 68, 587.
    • (1968) Chem. Rev. , vol.68 , pp. 587
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  • 45
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    • Lucken, E. A. C. J. Chem. Soc. 1959, 2954. It should be stressed that the MO formulation of eq 3 here does not correspond to the canonical MO formulation. Cf. ref 2a above, section 14-2, and: Harcourt, R. D. Chem. Phys. Lett. 1990, 167, 374.
    • (1959) J. Chem. Soc. , pp. 2954
    • Lucken, E.A.C.1
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    • Lucken, E. A. C. J. Chem. Soc. 1959, 2954. It should be stressed that the MO formulation of eq 3 here does not correspond to the canonical MO formulation. Cf. ref 2a above, section 14-2, and: Harcourt, R. D. Chem. Phys. Lett. 1990, 167, 374.
    • (1990) Chem. Phys. Lett. , vol.167 , pp. 374
    • Harcourt, R.D.1
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    • References 1-10 of section 14-2 of ref 2a above
    • (c) References 1-10 of section 14-2 of ref 2a above.
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    • July, 19
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