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0027164534
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For example: (a) Hendler, R. W.; Bose, S, K.; Shrager, R. I. Biophys. J. 1993, 65, 1307-1317. (b) Stultz, L. K.; Binstead, R. A.; Reynolds, M. S.; Meyer, T. J. J. Am. Chem. Soc. 1995, 117, 2520-2532.
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For example: (a) Hendler, R. W.; Bose, S, K.; Shrager, R. I. Biophys. J. 1993, 65, 1307-1317. (b) Stultz, L. K.; Binstead, R. A.; Reynolds, M. S.; Meyer, T. J. J. Am. Chem. Soc. 1995, 117, 2520-2532.
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0003228614
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19
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-
2542603570
-
-
note
-
Although the reaction mixture is transparent at λ > 300 nm under the studied conditions, at λ = 300-360 nm, the analysis is complicated by absorbante changes due to the formation of Cys-Cys.
-
-
-
-
24
-
-
2542644393
-
-
note
-
6 Not less than 95% of Cr(VI) was recovered by this method. The formation of Cys-Cys was shown qualitatively by IR spectroscopy. However, the quantitative determination of Cys-Cys is difficult because of its small concentration relative to unreacted Cys and its possible additional formation by autoxidation of Cys during the analytical procedures.
-
-
-
-
25
-
-
2542512109
-
-
note
-
More detailed studies of the region 350-380 nm (kinetic curves were acquired every 1 nm) did not reveal any shift of absorbance maximum (372 nm) for B in comparison with A.
-
-
-
-
26
-
-
2542557920
-
-
note
-
0, i.e., in the absolute majority of experiments (see Figure 3), it was not further analyzed in the current work.
-
-
-
-
27
-
-
0000108810
-
-
2 on the reactions of Cr(VI) with thiols, which was presumed to be connected with the formation of oxygen-sensitive Cr(II) intermediates, was recently reported: Perez-Benito, J. F.; Arias, C.; Lamrhari, D. New J. Chem. 1994, 18, 663-666.
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Lamrhari, D.3
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28
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2542524338
-
-
note
-
As was shown in separate experiments, such autoxidation did not take place in Ar-saturated solutions.
-
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29
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-
2542567017
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Bernasconi, C. F., Ed.; John Wiley & Sons: New York
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Bunnett, J. F. In Investigation of Rates and Mechanisms of Reactions. Part 1, 4th ed.; Bernasconi, C. F., Ed.; John Wiley & Sons: New York, 1986; p 238.
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Bunnett, J.F.1
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30
-
-
85088544514
-
-
note
-
- during the experiments was less than 10% (as determined from the absorbance changes at 510 nm).
-
-
-
-
31
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-
2542608086
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Boreham, C. J.; Buckingham, D. A.; Francis, D. J.; Sargeson, A. M.; Warner, L. G. J. Am. Chem. Soc. 1981, 103, 1975-1981.
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39
-
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85088542425
-
-
note
-
- is unlikely to play a significant role in the studied process.
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42
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0000774793
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44
-
-
85088545100
-
-
note
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6-8
-
-
-
-
45
-
-
85088544152
-
-
note
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0.
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46
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0001756341
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Kitagawa, S.; Seki, H; Kametani, F.; Sakurai H. Inorg. Chim. Acta 1988, 152, 251-255.
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2542571516
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Dillon, C. Ph.D. Thesis. University of Sydney, 1995.
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(1995)
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Dillon, C.1
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48
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-
85088542395
-
-
note
-
1 present in intracellular media.
-
-
-
-
49
-
-
0029988654
-
-
This hypothesis is supported by the recent observation that the isolated Cr(V)/GSH complex, unless activated by molecular oxygen, does not cause single-strand breaks in isolated DNA: Kortenkamp, A.; Casadevall, M.; Faux, S. P.; Jenner, A.; Shayer, R. O. J.; Woodbridge, N.; O'Brien, P. Arch. Biochem. Biophys. 1996, 329, 199-207.
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Kortenkamp, A.1
Casadevall, M.2
Faux, S.P.3
Jenner, A.4
Shayer, R.O.J.5
Woodbridge, N.6
O'Brien, P.7
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