Reaction of Stannocene and Plumbocene with Phosphenium Ions: Oxidative Addition of C—H Bonds to Low-Coordination-Number Main-Group Species

Journal of the American Chemical Society

Volumn 104, Issue 11, 1982, Pages 3239-3240

  Cowley, A H ^a   Kemp, R A ^a   Stewart, C A ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001687852     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00375a061     Document Type: Article

References (14)

1. Goldberg, D. E.; Harris, D. H.; Lappert, M. F.; Thomas, K. M. J. Chem. Soc., Chem. Commun. 1976,261–262.
2. Davidson, P. J.; Harris, D. H.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1976,2268–2274.
3. − follows the method pioneered by Parry and co-workers. See, e.g.: Thomas, M. G.; Schultz, C. W.; Parry, R. W. Inorg. Chem. 1977, 16, 994–1001.
4. −, see: Cowley, A. H.; Cushner, M. C.; Szobota, J. S. J. Am. Chem. Soc. 1978, 100, 7784–7786.
5. For the synthesis of stannocene, see: (a) Dave, L. D.; Evans, D. F.;Wilkinson, G. J. Chem. Soc. 1959,3684–3688.
6. Fischer, E. O.; Grubert, H. Z. Naturforsch. 1956, 11b, 423–424.
7. For the X-ray crystal structure of stannocene, see: Atwood, J. L.; Hunter, W. E.; Cowley, A. H.; Jones, R. A.; Stewart, C. A. J. Chem. Soc., Chem. Commun. 1981,925–927.
8. For the synthesis of plumbocene, see ref 3a, and Fischer (Fischer, E.O.; Grubert, H.Z. Anorg. Chem. 1956, 286, 237–242).
9. For the X-ray crystal structure of plumbocene, see: Panattoni, C.; Bombieri, G.; Croatto, U. Acta Crystallogr. 1966, 21, 823–826.
10. Akitt, J. W. Annu. Rep. NMR Spectrosc. 1972, 5, 465–556.
11. For an excellent review of the NMR aspects of prochiral assemblies, see: Jennings, W. B. Chem. Rev. 1975, 75, 307–322.
12. 2PCl, see: Cowley, A. H.; Kemp, R. A.; Wilburn, J. C. Inorg. Chem. 1981, 20, 4289–4293.
13. Cushner, M. C. Ph.D. Dissertation, The University of Texas at Austin, Austin, TX, 1979.
14. Dory, T. S.; Zuckerman, J. J.; Rausch, M. D. 182nd ACS National Meeting of the American Chemical Society, New York, NY, August 23–28, 1981; American Chemical Society: Washington, D.C., 1981; INOR 268.