Highly soluble complexes of [FeH6]4- and ion pairing interactions

Journal of Organometallic Chemistry

Volumn 554, Issue 2, 1998, Pages 171-173

  Linn Jr, Donald E ^a   Gibbins, Sidney G ^b  

^a INDIANA UNIVERSITY PURDUE UNIVERSITY FORT WAYNE   (United States)

^b UNIVERSITY OF VICTORIA   (Canada)

Author keywords

Ion pair; Iron; Soluble

Indexed keywords

EID: 0001687326     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0022-328x(97)00685-2     Document Type: Article

References (20)

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4. 9]: (a) A.P. Ginsberg, J. Miller, M. Koubek, J. Am. Chem. Soc. 83 (1961) 4909.
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7. 0.88.
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10. 1H COSY spectrum of the region between 4.5 and 1.2 δ showed cross peaks corresponding to the two methylene units in the bound THF. Complex (3) was prepared using the same procedure.
11. -' has been seen previously (see reference 4b).
12. 2] (see reference 4b).
13. 1=0 (see S.S. Zumdahl, R.S.J. Drago, Am. Chem. Soc. 89 (1967) 4319 and references therein).
14. -1 (calculated at the University of Victoria).
15. For examples of ion pairs in organometal reactions see: (a) M.Y. Darensbourg, P. Jimenez, J.R. Sacklet, J.M. Hackel, R.L. Kump, J. Am. Chem. Soc. 104 (1982) 152.
16. (b) K.H. Pannel, Y.S. Chen, K. Belknap, C.C. Wu, I. Benal, M.W. Creswick, H.N. Huang, Inorg. Chem. 22 (1983) 418.
17. Kosower E.M. J. Am. Chem. Soc. 80:1958;3253.
18. (a) W. Brönger, G. Auffermann, J. Alloys Comp. 219 (1995) 45-47.
19. (b) W. Brönger, G. Auffermann, Z. Anorg. Allg. Chem. 622 (1996) 1145.
20. (c) D. Bublitz, G. Peters, W. Preetz, G. Auffermann, Z. Anorg. Allg. Chem. 632 (1997) 184.