On the origin of matrix elements for electronic excitation (energy) transfer

Journal of Chemical Physics

Volumn 105, Issue 5, 1996, Pages 1897-1901

  Harcourt, Richard D ^a   Ghiggino, Kenneth P ^a   Scholes, Gregory D ^b   Speiser, Shammai ^c  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

^c TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001683188     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472060     Document Type: Article

References (22)

1. Th. Förster, Ann. Phys. 2, 55 (1948); Z. Naturforsch A 4, 321 (1949); in Modern Quantum Chemistry, edited by O. Sinanoglu (Academic, New York, 1965), Vol. 3.
2. Th. Förster, Ann. Phys. 2, 55 (1948); Z. Naturforsch A 4, 321 (1949); in Modern Quantum Chemistry, edited by O. Sinanoglu (Academic, New York, 1965), Vol. 3.
3. Th. Förster, Ann. Phys. 2, 55 (1948); Z. Naturforsch A 4, 321 (1949); in Modern Quantum Chemistry, edited by O. Sinanoglu (Academic, New York, 1965), Vol. 3.
4. D. L. Dexter, J. Chem. Phys. 21, 836 (1953).
5. (a) G. D. Scholes, K. P. Ghiggino, A. M. Oliver, and M. N. Paddon-Row, J. Phys. Chem. 97, 11871 (1993)
6. (b) S. Speiser, Chem. Rev. (in press).
7. G. D. Scholes and K. P. Ghiggino, J. Chem. Phys. 103, 8873 (1995).
8. R. D. Harcourt, G. D. Scholes, and K. P. Ghiggino, J. Chem. Phys. 101, 10521 (1994). In this reference, and in Refs. 6 and 7, the D and A chromophores were designated as A and B, respectively, and their associated orbitals as a, a*, b, and b* instead of d, d*, a, and a*.
9. G. D. Scholes, R. D. Harcourt, and K. P. Ghiggino, J. Chem. Phys. 102, 9574 (1995).
10. a′b′.
11. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
12. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
13. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
14. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
15. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
16. D. P. Craig and T. Thirunamachandran, Molecular Quantum Electrodynamics (Academic, New York, 1984); D. L. Andrews, Chem. Phys. 135, 195 (1989); D. L. Andrews and G. Juzeliunas, ibid 95, 5513 (1993); J. Phys. Chem. 96, 6606 (1992); G. D. Scholes, A. H. A. Clayton, and K. P. Ghiggino, ibid. 97, 7405 (1995); J. Avery, Int. J. Quantum Chem. 25, 79 (1984).
17. R. D. Harcourt and W. Roso, Can. J. Chem. 56, 1093 (1978); F. L. Skrezenek and R. D. Harcourt, J. Am. Chem. Soc. 106, 3934 (1984); R. D. Harcourt, J. Chem. Soc. Faraday Trans. 87, 1089 (1991); 88, 1119 (1992).
18. R. D. Harcourt and W. Roso, Can. J. Chem. 56, 1093 (1978); F. L. Skrezenek and R. D. Harcourt, J. Am. Chem. Soc. 106, 3934 (1984); R. D. Harcourt, J. Chem. Soc. Faraday Trans. 87, 1089 (1991); 88, 1119 (1992).
19. R. D. Harcourt and W. Roso, Can. J. Chem. 56, 1093 (1978); F. L. Skrezenek and R. D. Harcourt, J. Am. Chem. Soc. 106, 3934 (1984); R. D. Harcourt, J. Chem. Soc. Faraday Trans. 87, 1089 (1991); 88, 1119 (1992).
20. R. D. Harcourt and W. Roso, Can. J. Chem. 56, 1093 (1978); F. L. Skrezenek and R. D. Harcourt, J. Am. Chem. Soc. 106, 3934 (1984); R. D. Harcourt, J. Chem. Soc. Faraday Trans. 87, 1089 (1991); 88, 1119 (1992).
21. In Eq. (7), the effect of configuration interaction on the donor and acceptor wave functions has been omitted. The primary effect is to scale (Ref. 7) the value of the Coulomb integral J. This scaling need not be introduced in the present treatment in order to demonstrate the origins of the nature of the interactions with which we are concerned.
22. S. Levy and S. Speiser, J. Chem. Phys. 96, 3585 (1992).