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Volumn 15, Issue 5, 1996, Pages 1477-1487

CH3• is planar due to H-H steric repulsion. Theoretical study of MH3• and MH3Cl (M = C, Si, Ge, Sn)

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EID: 0001681968     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950560k     Document Type: Article
Times cited : (73)

References (111)
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    • In our approach, orbital energies occur naturally as a measure of (orbital) electronegativities of atoms or groups. Note that the trend in Pauling electronegativities for M, i.e., 2.55, 1.90, 2.01, and 1.96 for C, Si, Ge, and Sn, respectively, follows that of the AO energies and, in particular, that the irregular variation from Si via Ge to Sn correlates with the M-ns orbital energy (Figure 2). (b) Electronegativities were taken from: Boyd, R. J.; Markus, G. E. J. Chem. Phys. 1981, 75, 5385. (c) See also: Pauling, L. The Nature of the Chemical Bond; Cornell University Press: Ithaca, NY, 1960; Chapter 3.
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    • In our approach, orbital energies occur naturally as a measure of (orbital) electronegativities of atoms or groups. Note that the trend in Pauling electronegativities for M, i.e., 2.55, 1.90, 2.01, and 1.96 for C, Si, Ge, and Sn, respectively, follows that of the AO energies and, in particular, that the irregular variation from Si via Ge to Sn correlates with the M-ns orbital energy (Figure 2). (b) Electronegativities were taken from: Boyd, R. J.; Markus, G. E. J. Chem. Phys. 1981, 75, 5385. (c) See also: Pauling, L. The Nature of the Chemical Bond; Cornell University Press: Ithaca, NY, 1960; Chapter 3.
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