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Volumn 103, Issue 50, 1999, Pages 11028-11035

Effect of position of polyether attachment on the electron self-exchange activation barrier energies of redox polyether hybrid molten salts

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Indexed keywords


EID: 0001676409     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9925233     Document Type: Article
Times cited : (34)

References (49)
  • 1
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    • Jortner, J., Ratner, M. A., Eds.; IUPAC Series Chemistry for the 21st Century; Blackwell Science: Oxford, U.K.
    • (a) Terrill, R. H.; Murray, R. W. Molecular Electronics; Jortner, J., Ratner, M. A., Eds.; IUPAC Series Chemistry for the 21st Century; Blackwell Science: Oxford, U.K. 1997.
    • (1997) Molecular Electronics
    • Terrill, R.H.1    Murray, R.W.2
  • 21
    • 33646017917 scopus 로고    scopus 로고
    • note
    • 2a,24 of the chain lengths of the polyether tails. Thus, the rate constant fex in these melts is thought to represent a "contact" reaction, while the equilibrium δ is the appropriate distance representing the overall charge displacement from the contact electron transfer and ensuing motion of the complexes within their polyether shells. Additionally, the difference between equilibrium and contact δ in the present case is only ca. 1.5 Å.
  • 22
    • 85086353045 scopus 로고    scopus 로고
    • note
    • 3, 0.85 M, and 12.5 A; δ = 1.35 g/mol, C = 0.723 M, δ= 13.2 A; p = 1.37 g/mol, C = 0.84 M, δ= 12.5 A; p = 1.42 g/mol, C = 0.936 M, δ= 12.1 Å, respectively.
  • 23
    • 85086351862 scopus 로고    scopus 로고
    • note
    • -, A = area of electrode, D and C are the diffusion coefficient and concentration of electroactive species, respectively.
  • 28
    • 85086351524 scopus 로고    scopus 로고
    • note
    • 12b of the optical dielectric constant for an example redox polyether hybrid gave a constant within 10% of the polyether-alone value.
  • 29
    • 33646036289 scopus 로고    scopus 로고
    • Unpublished results, UNC
    • (b) Ritchie, J. Unpublished results, UNC, 1999.
    • (1999)
    • Ritchie, J.1
  • 31
    • 33646025456 scopus 로고    scopus 로고
    • University of North Carolina at Chapel Hill. Unpublished results
    • (a) Williams, M. B. University of North Carolina at Chapel Hill. Unpublished results, 1999.
    • (1999)
    • Williams, M.B.1
  • 32
    • 33646048529 scopus 로고    scopus 로고
    • Sulfonated counterions ion-pair to ligand-tailed metal complexes much more strongly than perchlorate counterions.
    • (b) Sulfonated counterions ion-pair to ligand-tailed metal complexes much more strongly than perchlorate counterions.
  • 33
    • 85086353106 scopus 로고    scopus 로고
    • note
    • 3d as 0.8 Å.
  • 34
    • 33646063738 scopus 로고    scopus 로고
    • Manuscript in preparation.
    • Ritchie, J. Manuscript in preparation.
    • Ritchie, J.1
  • 35
    • 33646060625 scopus 로고    scopus 로고
    • These materials behave as Newtonian fluids; i.e., measured viscosity does not vary with shear rate.
    • These materials behave as Newtonian fluids; i.e., measured viscosity does not vary with shear rate.
  • 40
    • 0003516749 scopus 로고
    • W. H. Freeman & Co.: New York
    • H is the hydrodynamic radius of a diffusion molecule in the following reference. Atkins, P. W. Physical Chemistry, 5th ed.; W. H. Freeman & Co.: New York, 1990; p 849.
    • (1990) Physical Chemistry, 5th Ed. , pp. 849
    • Atkins, P.W.1
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    • University of North Carolina at Chapel Hill. Unpublished results
    • Crooker, J. C. University of North Carolina at Chapel Hill. Unpublished results, 1997.
    • (1997)
    • Crooker, J.C.1
  • 43
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    • CION).
    • CION).
  • 47
    • 33646027818 scopus 로고    scopus 로고
    • Reference 18
    • Reference 18, p 850.
  • 49
    • 85086353040 scopus 로고    scopus 로고
    • M (0.68 and 0.93 for the Co,Ru-CI-tailed complexes, respectively), meaning that both ionic and electronic migration effects should be present.
    • M (0.68 and 0.93 for the Co,Ru-CI-tailed complexes, respectively), meaning that both ionic and electronic migration effects should be present.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.