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85037512848
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note
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We have also prepared several pyrene derivatives bearing cinnamyl and cinnamoyl groups. However, they were less reactive than 1a-c.
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27
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85037495161
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note
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+, 33).
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The fluorescence spectra of 1a,b, 3, and 5t in cyclohexane showed the weak intramolecular exciplex emission at a longer wavelength than the monomer fluorescence of pyrene. In the cases of 1c,d, the exciplex maxima were clearly observed at 450 and 470 nm, respectively.
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33
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33845281967
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For studies of fluorescence behavior of pyrene derivatives bearing electron-withdrawing or -releasing groups: (a) Swinnen, A. M.; Van der Auweraer, M.; DeSchryver, F. C.; Nakatani, K.; Okada, T.; Mataga, N. J. Am. Chem. Soc. 1987, 109, 321-330.
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