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Volumn 17, Issue 20, 1998, Pages 4523-4526

π-Back-bonding in Bis(isonitrile) complexes of rhodium(II) acetate: Structural analogs for rhodium carbenoids

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EID: 0001670614     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980066r     Document Type: Article
Times cited : (26)

References (31)
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    • For reviews, see: (a) Doyle, M. P. Aldrichim. Acta 1996, 29, 3. (b) Adams, J.; Spero, D. M. Tetrahedon 1991, 47, 1765. (c) Maas, G. Top. Curr. Chem. 1987, 737, 75. (d) Doyle, M. P. Chem. Rev. 1986, 86, 919. (e) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348.
    • (1996) Aldrichim. Acta , vol.29 , pp. 3
    • Doyle, M.P.1
  • 2
    • 0025976645 scopus 로고
    • For reviews, see: (a) Doyle, M. P. Aldrichim. Acta 1996, 29, 3. (b) Adams, J.; Spero, D. M. Tetrahedon 1991, 47, 1765. (c) Maas, G. Top. Curr. Chem. 1987, 737, 75. (d) Doyle, M. P. Chem. Rev. 1986, 86, 919. (e) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348.
    • (1991) Tetrahedon , vol.47 , pp. 1765
    • Adams, J.1    Spero, D.M.2
  • 3
    • 0002427539 scopus 로고
    • For reviews, see: (a) Doyle, M. P. Aldrichim. Acta 1996, 29, 3. (b) Adams, J.; Spero, D. M. Tetrahedon 1991, 47, 1765. (c) Maas, G. Top. Curr. Chem. 1987, 737, 75. (d) Doyle, M. P. Chem. Rev. 1986, 86, 919. (e) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348.
    • (1987) Top. Curr. Chem. , vol.737 , pp. 75
    • Maas, G.1
  • 4
    • 18444417883 scopus 로고
    • For reviews, see: (a) Doyle, M. P. Aldrichim. Acta 1996, 29, 3. (b) Adams, J.; Spero, D. M. Tetrahedon 1991, 47, 1765. (c) Maas, G. Top. Curr. Chem. 1987, 737, 75. (d) Doyle, M. P. Chem. Rev. 1986, 86, 919. (e) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348.
    • (1986) Chem. Rev. , vol.86 , pp. 919
    • Doyle, M.P.1
  • 5
    • 0012887591 scopus 로고
    • For reviews, see: (a) Doyle, M. P. Aldrichim. Acta 1996, 29, 3. (b) Adams, J.; Spero, D. M. Tetrahedon 1991, 47, 1765. (c) Maas, G. Top. Curr. Chem. 1987, 737, 75. (d) Doyle, M. P. Chem. Rev. 1986, 86, 919. (e) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348.
    • (1986) Acc. Chem. Res. , vol.19 , pp. 348
    • Doyle, M.P.1
  • 19
    • 85034284339 scopus 로고    scopus 로고
    • note
    • This argument is simplistic in that resonance effects, while primarily a π molecular orbital phenomenon, also affect σ molecular orbitals, though to a lesser degree. Likewise, inductive effects are not limited to σ molecular Orbitals but also affect π molecular orbitals. These complex interdependencies highlight the difficulties inherent in relying on bond lengths to measure the degree of π-back-bonding present in the isonitrile complexes.
  • 28
    • 0001629519 scopus 로고
    • Wiley: New York
    • (b) Ugi, I.; Meyr, R. Organic Syntheses; Wiley: New York, 1973; Collect. Vol. 5, p 1060.
    • (1973) Organic Syntheses , vol.5 COLLECTIVE VOLUME , pp. 1060
    • Ugi, I.1    Meyr, R.2


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