Chlorination of Icosahedral Carborane Anions. X-ray Crystal Structure of [Me3NH][CH3-1-CB11Cl11]

Inorganic Chemistry

Volumn 36, Issue 11, 1997, Pages 2246-2247

  Xie, Zuowei ^a   Tsang, Chi Wing ^a   Xue, Feng ^a   Mak, Thomas C W ^a  

^a CHINESE UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001668149     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9614935     Document Type: Article

References (20)

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16. -1, KBr): 3082 (m, br), 2803 (s), 1095 (s), 1035 (vs), 981 (s), 541(m). LSIMS for 1: m/e 535.9. Found: m/e 535.8. The expected isotopic distribution of masses is also observed in LSIMS.
17. Jelinek, T.; Baldwin, P.; Scheidt, W. R.; Reed, C. A. Inorg. Chem. 1993, 12, 1982.
18. w = 0.053, data to parameter ratio 12.4. Data were collected at 294 K on a MSC/Rigaku RAXIS-IIC image plate using Mo Kα radiation (λ = 0.71073 Å) from a Rigaku rotating-anode X-ray generator operating at 50 kV and 90 mA. The structure was solved by direct methods and refined using the Siemens SHELXTL PLUS program package (PC version) (SHELXTL PLUS program set; Siemens Analytical X-ray Instruments, Inc., Madison, WI, 1990). The icosahedral cage is defined by four independent B atoms and the four independent Cl atoms representing the exohedral groups which are each assigned the same occupancy factor of (6 + 11 × 7)/(12 × 7) = 0.946.
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