Crystal structures of a family of new copper(I) cyanide complexes of thiourea and substituted thioureas

Inorganic Chemistry

Volumn 35, Issue 11, 1996, Pages 3145-3153

  Stocker, Fred B ^a   Troester, Melissa A ^a,c   Britton, Doyle ^b  

^a MACALESTER COLLEGE   (United States)

^b UNIVERSITY OF MINNESOTA   (United States)

^c UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001651063     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9511027     Document Type: Article

References (41)

1. Stocker, F. B. Inorg. Chem. 1991, 30, 1472
2. 3Cl).
3. 4).
4. 2).
5. 2Cl).
6. 3Cl).
7. 0 5).
8. 2O).
9. 2).
10. 2O).
11. 0 5).
12. 2).
13. (l) Jain, A. K.; Smith, A. J. Inorg. Nucl. Chem. Lett. 1974, 10, 707 (preparation and structure of Cu(tu)(o-phen)I).
14. 2O).
15. 2O).
16. 3).
17. 4)).
18. 0 5).
19. (r) Eller, P. G.; Bradley, D. C.; Hursthouse, M. B.; Meek, D. W. Coord. Chem. Rev. 1977, 24, 56-63 (an extensive review of Cu(I) complexes of tu and substituted thiourea derivatives).
20. 2(o-phen)I.
21. 0 5).
22. 2O).
23. 2O).
24. 3).
25. 3).
26. At increased CuCN concentrations, a crystalline complex forms. The composition, properties, and crystal structure of this new complex will be reported in the literature in the near future.
27. See footnote 2(1), p 708, where this interference was cited.
28. We are indebted to Macalester student Lilla Bartkó for assistance in the preparation of complexes 5 and 7.
29. MITHRIL: Gilmore, C. J. J. Appl. Crystallogr. 1984 17, 42.
30. DIRDIF: Beurskens, P. T. Technical Report 1984/1 Crystallography Laboratory, Toernooiveld, 6525 Ed Nijmegen, Netherlands.
31. (a) Cromer, D. T.; Waber, J. T. International Tables for X-ray Crystallography; The Kynoch Press: Birmingham, England, 1974; Vol. IV, Table 2.2A;
32. (b) Cromer, D. T. Ibid. Table 2 3.1.
33. TEXSAN-TEXRAY Structure Analysis Package, Molecular Structure Corporation, 1985.
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37. See the article cited in footnote 1 for a full set of references on crystal structures of CuCN complexes published through 1990. Reference to a more recently reported CuCN complex can be found in footnote 12.
38. Swammathan, K.; Irving, H. M. N. H J. Inorg. Nucl. Chem. 1964, 26, 1291.
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