Asymmetric hydrogenation of ethyl pyruvate: Diffusion effects on enantioselectivity

Journal of Catalysis

Volumn 161, Issue 2, 1996, Pages 759-765

  Sun, Yongkui ^a   Wang, Jian ^a   LeBlond, Carl ^a   Landau, Ralph N ^a,b   Blackmond, Donna G ^a,c  

^a MERCK RESEARCH LABORATORIES   (United States)

^b Sandoz Pharma Ltd   (Switzerland)

^c MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001632585     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1006/jcat.1996.0238     Document Type: Article

References (28)

1. Orito, Y., Imai, S., and Niwa, S., J. Chem. Soc. Jpn. 1118 (1979).
2. Garland, M., and Blaser, H. U., JACS 112, 7048 (1990).
3. Blaser, H. U., Garland, M., and Jallet, H. P., J. Catal. 144, 569 (1993).
4. Wehrli, J. T., Baiker, A., Monti, D. M., and Blaser, H. U., J. Mol. Catal. 49, 195 (1989).
5. Wehrli, J. T., Baiker, A., Monti, D. M., Blaser, H. U., and Jalett, H. P., J. Mol. Catal. 57, 245 (1989).
6. Wehrli, J. T., Baiker, A., Monti, D. M., and Blaser, H. U., J. Mol. Catal. 61, 207 (1990).
7. Garland, M., Jalett, H. P., and Blaser, H. U., in "Heterogeneous Catalysis and Fine Chemicals" (M. Guisnet et al., Eds.), Vol. 2, p. 177. Elsevier Science, Amsterdam, 1991.
8. Minder, B., Mallat, T., Skrabal, P., and Baiker, A., Catal. Lett. 29, 115 (1994).
9. Wang, G., Heinz, T., Pfaltz, A., Minder, B., Mallat, T., and Baiker, A., JCS Chem. Commun. 2047 (1994).
10. Minder, B., Mallat, T., Baiker, A., Wang, G., Heinz, T., and Pfaltz, A., J. Catal. 154, 371 (1995).
11. Simons, K. E., Wang, G., Heinz, T., Pfaltz, A., and Baiker, A., Tetrahedron Asymmetry 6, 505 (1995).
12. Sutherland, I. M., Ibbotson, A., Moyes, R. B., and Wells, P. B., J. Catal. 125, 77 (1990).
13. Sutherland, Meheux, P. A., Ibbotson, A., and Wells, P. B., J. Catal. 128, 387 (1991).
14. Simons, K. E., Ibbotson, A., Johnston, P., Plum, H., and Wells, P. B., J. Catal. 150, 321 (1994).
15. Bond, G., and Wells, P. B., J. Catal. 150, 329 (1994).
16. Margitfalvi, J. L., in "Catalysis of Organic Reactions" ed. by (M. G. Scaros and M. L. Prunier, Eds.), p. 201. Dekker, New York, 1995.
17. Augustine, R. L., Tanielyan, S. K., and Doyle, L. K., Tetrahedron Asymmetry 4, 1803 (1993).
18. Toth, G., Kovacs, A., Tarnai, T., and Tungler, A., Tetrahedron Asymmetry 4, 331 (1993).
19. Singh, U. K., Landau, R. N., Sun, Y., LeBlond, C., Blackmond, D. G., Tanielyan, S. K., and Augustine, R. L., J. Catal. 154, 91 (1995).
20. Sun, Y., Landau, R. N., Wang, J., LeBlond, C., and Blackmond, D. G., J. Am. Chem. Soc. 118, 1348 (1996).
21. Roberts, G. W., in "Catalysis in Organic Synthesis 1976" (P. N. Rylander and H. Greenfield, Eds.), p. 1. Academic Press, New York, 1976.
22. Paul, E. L., Chem. Eng. Sci. 43, 1773 (1988).
23. Roberts, G. W., and Lamb, H. H., J. Catal. 154, 364 (1995).
24. Koros, R. M., and Nowak, E. J., Chem. Eng. Sci. 22, 470 (1967).
25. Madon, R. J., and Boudart, M., Ind. Eng. Chem. Fund. 21, 438 (1982).
26. Landau, R. N., Singh, U. K., Gortsema, F. P., Sun, Y., Blackmond, D. G., Gomolka, S. C., Lam, T., and Futran, M., J. Catal. 157, 201 (1995).
27. Deimling, A., Karandikar, B. M., Shah, Y. T., and Carr, N. L., Chem. Eng. J. 29, 140 (1984).
28. We found no product inhibition in ethyl pyruvate hydrogenation under any conditions; see Wang, J., LeBlond, C., Sun, Y., Landau, R. N., and Blackmond, D. G., J. Catal., 161, 752 (1996).